275794
三(三甲基硅基)磷
≥98%
别名:
磷酸三(三甲基硅基)酯
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关于此项目
线性分子式:
[(CH3)3SiO]3P(O)
化学文摘社编号:
分子量:
314.54
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
234-028-1
Beilstein/REAXYS Number:
1794624
MDL number:
产品名称
三(三甲基硅基)磷, ≥98%
InChI key
QJMMCGKXBZVAEI-UHFFFAOYSA-N
InChI
1S/C9H27O4PSi3/c1-15(2,3)11-14(10,12-16(4,5)6)13-17(7,8)9/h1-9H3
SMILES string
C[Si](C)(C)OP(=O)(O[Si](C)(C)C)O[Si](C)(C)C
assay
≥98%
form
liquid
greener alternative product characteristics
Design for Energy Efficiency
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refractive index
n20/D 1.409 (lit.)
bp
228-229 °C/720 mmHg (lit.)
mp
3-4 °C (lit.)
density
0.945 g/mL at 25 °C (lit.)
greener alternative category
Quality Level
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General description
已经研究了三(三甲基甲硅烷基)磷酸酯作为LiNi0.5Co0.2Mn0.3O2 的新型成膜添加剂，用于在LiPF6电解质中以高截止电位循环。 三(三甲基甲硅烷基)磷酸酯[磷酸的三(三甲基甲硅烷基)酯]与环铝氮烷发生脱烷基甲硅烷基化反应，得到杂金刚烷分子。
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signalword
Danger
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
55.4 °F - closed cup
flash_point_c
13 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
The use of [18O4]phosphoric acid in the quantitation of phosphate by gas-liquid chromatography-mass spectrometry analysis.
G Graff et al.
Analytical biochemistry, 107(2), 324-331 (1980-09-15)
Jiri Pinkas et al.
Inorganic chemistry, 41(25), 6914-6918 (2002-12-10)
A dealkylsilylation reaction between alumazene [2,6-(i-Pr)(2)C(6)H(3)NAlMe](3) (1) and tris(trimethylsilyl) ester of phosphoric acid (2) in a 1:3 molar ratio provides the heteroadamantane molecule (MeAl)[2,6-(i-Pr)(2)C(6)H(3)N](3)[Al[OP(OSiMe(3))(3)]](2)(O(3)POSiMe(3)) (3). Compound 3 was characterized by analytical and spectroscopic methods, and its molecular structure was established
A Garcia-Casas et al.
Colloids and surfaces. B, Biointerfaces, 181, 973-980 (2019-08-07)
Sol-gel coatings are proposed as surface treatments for titanium-based materials to promote the osseointegration of prosthetic devices with the host. As precursors of sol-gel synthesis, two silanes were selected: 3-methacryloxypropyltrimethoxy silane and 2 tetramethyl orthosilane. Sol-gel synthesis was functionalized with
Tris (trimethylsilyl) phosphate: A film-forming additive for high voltage cathode material in lithium-ion batteries.
Yan G, et al.
Journal of Power Sources, 248, 1306-1311 (2014)
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