277053
(S)-(+)-2-(甲氧基甲基)吡咯烷
99%
别名:
O-甲基-L-脯氨醇, SMP
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经验公式（希尔记法）:
C6H13NO
化学文摘社编号:
分子量:
115.17
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587324
产品名称
(S)-(+)-2-(甲氧基甲基)吡咯烷, 99%
InChI
1S/C6H13NO/c1-8-5-6-3-2-4-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1
SMILES string
COC[C@@H]1CCCN1
InChI key
CHPRFKYDQRKRRK-LURJTMIESA-N
assay
99%
form
liquid
optical activity
[α]20/D +2.4°, c = 2 in benzene
refractive index
n20/D 1.4457 (lit.)
bp
62 °C/40 mmHg (lit.)
density
0.933 g/mL at 25 °C (lit.)
functional group
ether
Application
手性助剂，用于不对称合成炔丙醇 和 4-硝基环己酮， 以及用于不对称 Michael 加成反应生成烯酮。
(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
113.0 °F - closed cup
flash_point_c
45 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
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