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Merck
CN

277053

Sigma-Aldrich

(S)-(+)-2-(甲氧基甲基)吡咯烷

99%

别名:

O-甲基-L-脯氨醇, SMP

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关于此项目

经验公式(希尔记法):
C6H13NO
CAS Number:
分子量:
115.17
Beilstein:
3587324
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
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方案

99%

表单

liquid

旋光性

[α]20/D +2.4°, c = 2 in benzene

折射率

n20/D 1.4457 (lit.)

沸点

62 °C/40 mmHg (lit.)

密度

0.933 g/mL at 25 °C (lit.)

官能团

ether

SMILES字符串

COC[C@@H]1CCCN1

InChI

1S/C6H13NO/c1-8-5-6-3-2-4-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1

InChI key

CHPRFKYDQRKRRK-LURJTMIESA-N

应用

手性助剂,用于不对称合成炔丙醇 和 4-硝基环己酮, 以及用于不对称 Michael 加成反应生成烯酮。
(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.

象形图

FlameExclamation mark

警示用语:

Warning

危险分类

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

113.0 °F - closed cup

闪点(°C)

45 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

新产品

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Stereocontrolled Addition Reaction of Organometallics to Chiral a-Keto Amides.
Fujisawa T, et al.
Bulletin of the Chemical Society of Japan, 63(7), 1894-1897 (1990)
Synthesis, 1242-1242 (1992)
Joseph G Jardine et al.
PLoS pathogens, 12(8), e1005815-e1005815 (2016-08-26)
An optimal HIV vaccine should induce broadly neutralizing antibodies (bnAbs) that neutralize diverse viral strains and subtypes. However, potent bnAbs develop in only a small fraction of HIV-infected individuals, all contain rare features such as extensive mutation, insertions, deletions, and/or
Jingyu Wang et al.
Polymers, 11(4) (2019-04-10)
Conventional endovascular embolization of intracranial (or brain) aneurysms using helical detachable platinum coils can be time-consuming and occasionally requires retreatment due to incomplete coil packing. These shortcomings create a need for new biomedical devices and methods of achieving brain aneurysm
Direct organocatalytic aldol reactions in buffered aqueous media.
Cordova A, et al.
Chemical Communications (Cambridge, England), 24, 3024-3025 (2002)

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