277053
(S)-(+)-2-(甲氧基甲基)吡咯烷
99%
别名:
O-甲基-L-脯氨醇, SMP
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关于此项目
经验公式(希尔记法):
C6H13NO
CAS Number:
分子量:
115.17
Beilstein:
3587324
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
方案
99%
表单
liquid
旋光性
[α]20/D +2.4°, c = 2 in benzene
折射率
n20/D 1.4457 (lit.)
沸点
62 °C/40 mmHg (lit.)
密度
0.933 g/mL at 25 °C (lit.)
官能团
ether
SMILES字符串
COC[C@@H]1CCCN1
InChI
1S/C6H13NO/c1-8-5-6-3-2-4-7-6/h6-7H,2-5H2,1H3/t6-/m0/s1
InChI key
CHPRFKYDQRKRRK-LURJTMIESA-N
应用
手性助剂,用于不对称合成炔丙醇 和 4-硝基环己酮, 以及用于不对称 Michael 加成反应生成烯酮。
(S)-(+)-2-(Methoxymethyl)pyrrolidine may be used to prepare planar chiral 2-phospha[3]ferrocenophanes. It may also be used as an organocatalyst in the cross-aldol reaction of dihydroxyacetone with p-nitrobenzaldehyde to form the corresponding polyol. SMP reacts with benzoylformic acid to form (S)-N-benzoylformyl-2-(methoxymethyl)-pyrrolidine.
警示用语:
Warning
危险分类
Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
113.0 °F - closed cup
闪点(°C)
45 °C - closed cup
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
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