277592
9-乙烯基咔唑
98%
别名:
9-乙烯基-9H-咔唑, N-乙烯基咔唑
方案
98%
沸点
154-155 °C/3 mmHg (lit.)
mp
60-65 °C (lit.)
SMILES字符串
C=Cn1c2ccccc2c3ccccc13
InChI
1S/C14H11N/c1-2-15-13-9-5-3-7-11(13)12-8-4-6-10-14(12)15/h2-10H,1H2
InChI key
KKFHAJHLJHVUDM-UHFFFAOYSA-N
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一般描述
9-乙烯基咔唑(9-VC)是一种单体化合物，具有光化学特性、热稳定性和乙烯基带来的高反应性。它可提高导电聚合物与热固性树脂的性能。在药物递送体系中，9-乙烯基咔唑可促进药剂包封，实现控释并提高药效，尤其适于癌症治疗。它的光化学能力有助于光子器件发展。
应用
9-乙烯基咔唑可用于：
- 作为单体与3,4-乙烯二氧噻吩(EDOT)合成电致变色导电薄膜共聚物，用于智能窗和柔性电子显示器。
- 作为前体制备共聚物，用于制造高量子效率的聚合热活化延迟荧光(TADF)有机发光二极管(OLED)。
- 作为功能单体经由无表面活性剂乳液聚合制备聚乙烯咔唑(p(VC))微凝胶颗粒。这种微凝胶可用于药物递送和组织工程领域。
- 作为前体制作钙钛矿太阳能电池的空穴传输层。
警示用语：
Danger
危险分类
Acute Tox. 2 Oral - Acute Tox. 4 Dermal - Aquatic Acute 1 - Aquatic Chronic 1 - Muta. 2 - Skin Irrit. 2 - Skin Sens. 1
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Merve Kara et al.
Macromolecular rapid communications, 36(23), 2070-2075 (2015-09-12)
A new phenacyl-type photoinitiator based on ethyl carbazole as a long wavelength photo-initiator is developed for free radical polymerization. Phenacyl ethyl carbazolium hexafluoroantimonate (PECH) photoinitiator is synthesized in a two-step, one-pot manner by quaternizing ethyl carbazole with phenacyl bromide and
Ceren Kütahya et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 26(46), 10444-10451 (2020-04-29)
NIR exposure at 790 nm activated photopolymerization of monomers comprising UV-absorbing moieties by using [CuII /(TPMA)]Br2 (TPMA=tris(2-pyridylmethyl)amine) in the ppm range and an alkyl bromide as initiator. Some of them comprised structural elements selected either from those showing proton transfer or
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