278041
叔丁基丙二酸二乙酯
96%
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关于此项目
线性分子式:
(CH3)3CCH(COOC2H5)2
化学文摘社编号:
分子量:
216.27
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-067-5
Beilstein/REAXYS Number:
1781709
MDL number:
Assay:
96%
Form:
liquid
InChI key
RJNICNBRGVKNSR-UHFFFAOYSA-N
InChI
1S/C11H20O4/c1-6-14-9(12)8(11(3,4)5)10(13)15-7-2/h8H,6-7H2,1-5H3
SMILES string
CCOC(=O)C(C(=O)OCC)C(C)(C)C
assay
96%
form
liquid
Quality Level
bp
102-104 °C/11 mmHg (lit.)
density
1.014 g/mL at 25 °C (lit.)
functional group
ester
Application
Diethyl tert-butylmalonate has been used in the preparation of enantiomers of 4-tert-butyl-3-isopropyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2]octane 1-sulfide (TBIPPS).
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
199.4 °F - closed cup
flash_point_c
93 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
X L Ju et al.
Bioorganic & medicinal chemistry, 8(9), 2337-2341 (2000-10-12)
The enantiomers of 4-tert-butyl-3-isopropyl-2,6,7-trioxa-1-phosphabicyclo[2.2.2 ]octane 1-sulfide (TBIPPS) were prepared in nine steps from diethyl tert-butylmalonate, and their abilities to compete with [3H]1-(4-ethynylphenyl)-4-n-propyl-2,6,7-trioxabicyclo[2.2.2 ]octane (EBOB), a noncompetitive antagonist of ionotropic gamma-aminobutyric acid (GABA) receptors, at their binding site were investigated using
Grazia Luisi et al.
Antioxidants (Basel, Switzerland), 8(1) (2018-12-28)
Oxidative damage is among the factors associated with the onset of chronic pathologies, such as neurodegenerative and metabolic diseases. Several classes of anti-oxidant compounds have been suggested as having a protective role against cellular stressors, but, in this perspective, peptides'
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