Quality Level
assay
97%
form
liquid
refractive index
n20/D 1.596 (lit.)
bp
141-142 °C/30 mmHg (lit.)
density
1.091 g/mL at 25 °C (lit.)
SMILES string
c1ccc(cc1)-n2cccn2
InChI
1S/C9H8N2/c1-2-5-9(6-3-1)11-8-4-7-10-11/h1-8H
InChI key
WITMXBRCQWOZPX-UHFFFAOYSA-N
General description
1-苯基吡唑可与三氯化铑进行环金属化反应，生成rac-二（μ-氯）四[2-（吡唑-1-基）苯基-C1和N2′]双铑。副产物HOAc自催化的1-苯基吡唑的C-H键活化已被研究。
Application
1-苯吡唑已被用于：
- 制备4,5-二苯基吡唑并[1,5-a]喹啉、1-（1,2,3,4-四苯基萘-5-基）吡唑和1-（1,2,3,4,5,6,7,8-八苯基蒽-9-基）吡唑
- 作为环金属配体用于制备新型杂配铱（III）配合物
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Nobuyoshi Umeda et al.
The Journal of organic chemistry, 76(1), 13-24 (2010-12-15)
The direct oxidative coupling of phenylazoles with internal alkynes proceeds efficiently in the presence of a rhodium catalyst and a copper oxidant accompanied by double or quadruple C-H bond cleavages. Thus, as a representative example, 4,5-diphenylpyrazolo[1,5-a]quinoline, 1-(1,2,3,4-tetraphenylnaphthalen-5-yl)pyrazole, and 1-(1,2,3,4,5,6,7,8-octaphenylanthracen-9-yl)pyrazole can
Cyclometallated compounds: VII. X-Ray crystal structure of the product of cyclometallation of 1-phenylpyrazole with rhodium trichloride.
Steel PJ.
Journal of Organometallic Chemistry, 408(3), 395-402 (1991)
Jian-ning Yu et al.
Guang pu xue yu guang pu fen xi = Guang pu, 30(9), 2424-2427 (2010-11-26)
New heteroleptic iridium(III) complexes (ppz)2Ir(LX), which consist of two cyclometalated ligands ppz(1-phenylpyrazole) together with an ancillary ligand LX (LX= 2-(2'-hydroxylphenyl)benzothiazole (BTZ), 2-(3'-methyl-2'-hydroxylphenyl) benzothiazole (3-MeBTZ), 2-(4'-methyl-2'-hydroxylphenyl) benzothiazole (4-MeBTZ) and 2-(4'-Trifluoromethyl-2'hydroxylphenyl) benzothiazole (4-tfmBTZ)), were synthesized and characterized. The molecular structures and photophysical
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 278289-5G | 04061826203170 |