278394
3,5-二甲基-1-己炔-3-醇
98%
别名:
3,5-二甲基-1-己炔-3-醇, 3,5-二甲基己炔-3-醇
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关于此项目
线性分子式:
(CH3)2CHCH2C(CH3)(OH)C≡CH
化学文摘社编号:
分子量:
126.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
203-500-9
MDL number:
Assay:
98%
Form:
liquid
产品名称
3,5-二甲基-1-己炔-3-醇, 98%
InChI key
NECRQCBKTGZNMH-UHFFFAOYSA-N
InChI
1S/C8H14O/c1-5-8(4,9)6-7(2)3/h1,7,9H,6H2,2-4H3
SMILES string
CC(C)CC(C)(O)C#C
vapor density
4.34 (vs air)
vapor pressure
4.5 mmHg ( 20 °C)
assay
98%
form
liquid
refractive index
n20/D 1.434 (lit.)
bp
150-151 °C (lit.)
density
0.859 g/mL at 25 °C (lit.)
functional group
hydroxyl
Quality Level
Application
3,5-二甲基-1-己炔-3-醇可用于：
- 合成 3,5-二甲基-1-苯基-1-己烯-3-醇通过一锅钯介导的氢化氨基化/Stille 交叉 -耦合。
- 在中性离子液体（1-丁基-3-甲基咪唑四氟硼酸盐）中通过酯化反应合成 3,5-二甲基-1-己炔-3-乙酸酯。
- 通过 抗-Markovnikov 加成苯甲酸合成 3,5-二甲基-3-羟基-1-己烯-1-基苯甲酸酯。
General description
用相对速率法测定了羟基自由基 (OH) 与 3, 5-二甲基-1-己基-3-醇反应的双分子速率常数 。研究了 CuCl 在不同离子液体和溶剂中催化 CO 2 与 3，5-二甲基-1-己炔-3-醇的反应 。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
111.2 °F - closed cup
flash_point_c
44 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
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European Journal of Organic Chemistry, 2000(13), 2361-2366 (2000)
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International Journal of Chemical Kinetics, 36(10), 534-544 (2004)
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