279676
(1S)-(-)-樟脑
99%
别名:
(-)-樟脑, (1S)-1,7,7-三甲基二环[2.2.1]庚烷-2-酮
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关于此项目
经验公式（希尔记法）:
C10H16O
化学文摘社编号:
分子量:
152.23
UNSPSC Code:
12352115
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-354-7
Beilstein/REAXYS Number:
1907612
MDL number:
产品名称
(1S)-(-)-樟脑, 99%
InChI key
DSSYKIVIOFKYAU-OIBJUYFYSA-N
InChI
1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m0/s1
SMILES string
[H][C@]12CC[C@](C)(C(=O)C1)C2(C)C
vapor density
5.24 (vs air)
vapor pressure
4 mmHg ( 70 °C)
assay
99%
optical activity
[α]20/D −43°, c = 10 in ethanol
autoignition temp.
870 °F
expl. lim.
3.5 %
bp
204 °C (lit.)
mp
177-179 °C (lit.)
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Application
手性中间体和手性助剂前体。用于合成高效甜味剂。
General description
(1S)-(-)-樟脑是一种在许多植物精油中发现的单萜类化合物。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 1
flash_point_f
149.0 °F - closed cup
flash_point_c
65 °C - closed cup
ppe
Eyeshields, Gloves, type P3 (EN 143) respirator cartridges
Journal of Agricultural and Food Chemistry, 39, 52-52 (1991)
Determination of the enantiomeric composition of (1R)(+)-and (1S)(-)-camphor in essential oils of some Lamiaceae and compositae herbs.
Flavour and Fragrance Journal, 8(4), 225-228 (1993)
The essential oil of Achillea falcata L.
Kurkcuoglu M, et al.
Flavour and Fragrance Journal, 18(3), 192-194 (2003)
Tetrahedron Letters, 32, 2339-2339 (1991)
Guangling Bian et al.
Chirality, 24(10), 825-832 (2012-06-30)
A series of new camphorsulfonylated ligands derived from chiral 2-amino-2'-hydroxy-1,1'-binaphthyl (NOBIN) and (+)-camphorsulfonic acid were synthesized by a short and simple synthetic sequence, and their enantioselective catalytic activities were assessed in the nucleophilic addition reaction of dialkylzinc reagents to aldehydes
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