280895
4-溴重氮苯四氟化硼酸盐
96%
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关于此项目
线性分子式:
BrC6H4N2BF4
化学文摘社编号:
分子量:
270.82
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-608-2
Beilstein/REAXYS Number:
3791621
MDL number:
Assay:
96%
InChI key
FXTCQUCYDJZGGU-UHFFFAOYSA-N
InChI
1S/C6H4BrN2.BF4/c7-5-1-3-6(9-8)4-2-5;2-1(3,4)5/h1-4H;/q+1;-1
SMILES string
F[B-](F)(F)F.Brc1ccc(cc1)[N+]#N
assay
96%
mp
135-140 °C (dec.) (lit.)
functional group
bromo
storage temp.
2-8°C
General description
已经研究了4-溴苯重氮四氟硼酸盐的电化学还原反应，用于碳毡的衍生化（改性碳表面，无论是玻璃碳还是碳毡）。
Application
4-溴苯基重氮四氟硼酸盐被用于制备：
- 表面改性的Au(111)电极
- 1-(4′-溴苯基)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-十七氟代-1-烯
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
Bo Cui et al.
Langmuir : the ACS journal of surfaces and colloids, 29(9), 2955-2960 (2013-02-16)
Surface modifications of a Au(111) electrode with 4-bromobenzenediazonium tetrafluoroborate (BBD) in acetonitrile (ACN) and 0.1 M HClO4 have been characterized by scanning tunneling microscopy (STM). In ACN, STM results reveal the formation of disordered thin organic films. The involvement of
Electrochemical attachment of organic groups to carbon felt surfaces.
Coulon E, et al.
Langmuir, 17(22), 7102-7106 (2001)
Efficient access to perfluoroalkylated aryl compounds by Heck reaction.
Darses S, et al.
European Journal of Organic Chemistry, 2001(6), 1121-1128 (2001)
Younghee Park et al.
ACS applied materials & interfaces, 12(36), 40870-40878 (2020-08-19)
Although surface engineering has been regarded to be a great approach to modulate the optical and electrical properties of nanomaterials, the spontaneous covalent functionalization on semiconducting 2H-MoS2 is a notoriously difficult process, while several reactions have been performed on metallic
Tomonari Shiraishi et al.
Nanoscale, 9(43), 16900-16907 (2017-10-28)
Single-walled carbon nanotubes (SWNTs) with local chemical modification have been recognized as a novel near infrared (NIR) photoluminescent nanomaterial due to the emergence of a new red-shifted photoluminescence (PL) with enhanced quantum yields. As a characteristic feature of the locally
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