281069
氮杂环丁烷
98%
别名:
三亚甲基亚胺
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关于此项目
经验公式（希尔记法）:
C3H7N
化学文摘社编号:
分子量:
57.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
207-963-8
Beilstein/REAXYS Number:
102384
MDL number:
产品名称
氮杂环丁烷, 98%
InChI key
HONIICLYMWZJFZ-UHFFFAOYSA-N
InChI
1S/C3H7N/c1-2-4-3-1/h4H,1-3H2
SMILES string
C1CNC1
assay
98%
form
liquid
refractive index
n20/D 1.432 (lit.)
bp
61-62 °C (lit.)
density
0.847 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
氮杂环丁烷用于：
- 高产率钯催化与芳基溴化物的交叉偶联反应
- 碘硝基阳离子的Ullmann型偶联反应
General description
本文研究了氮杂环丁烷自由基丁烷自由基阳离子在λ= 436 nm的光作用下的光化反应。测定了氮杂环丁烷在固体氩基质中的红外光谱。
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-4.0 °F
flash_point_c
-20 °C
ppe
Faceshields, Gloves, Goggles
法规信息
危险化学品
此项目有
Synthesis, 3245-3245 (2006)
Synthesis, 243-243 (2007)
Experimental and computational studies of the structure and vibrational spectra of azetidine derivatives.
Thompson CA, et al.
Journal of Molecular Structure, 491(1), 67-80 (1999)
Phototransformations of azetidine radical cations stabilized in freonic matrices.
Sorokin ID, et al.
High Energy Chemistry, 48(3), 180-184 (2014)
Younghue Han et al.
Journal of medicinal chemistry, 55(18), 8188-8192 (2012-09-04)
Novel azetidines based on the 3-aryl-3-oxypropylamine scaffold were designed, synthesized, and evaluated as TRIs. Reduction of 1 followed by Swern oxidation and then Grignard reaction gave 3. The alkylation of 3 provided the corresponding azetidine derivatives 6, of which the
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