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281069

氮杂环丁烷

Name: 氮杂环丁烷
Brand: ALDRICH

98%

别名:

三亚甲基亚胺

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关于此项目

经验公式（希尔记法）:

C₃H₇N

化学文摘社编号:

503-29-7

分子量:

57.09

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24856966

EC Number:

207-963-8

Beilstein/REAXYS Number:

102384

MDL number:

MFCD00005165

Assay:

98%

Form:

liquid

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Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.432 (lit.)

bp

61-62 °C (lit.)

density

0.847 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

C1CNC1

InChI

1S/C3H7N/c1-2-4-3-1/h4H,1-3H2

InChI key

HONIICLYMWZJFZ-UHFFFAOYSA-N

General description

本文研究了氮杂环丁烷自由基丁烷自由基阳离子在λ= 436 nm的光作用下的光化反应。测定了氮杂环丁烷在固体氩基质中的红外光谱。

Application

氮杂环丁烷用于：

高产率钯催化与芳基溴化物的交叉偶联反应
碘硝基阳离子的Ullmann型偶联反应

pictograms

GHS02,GHS05

signalword

Danger

hcodes

H225,H314

pcodes

P210 - P233 - P240 - P280 - P303 + P361 + P353 - P305 + P351 + P338

Hazard Classifications

Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-4.0 °F

flash_point_c

-20 °C

ppe

Faceshields, Gloves, Goggles

法规信息

危险化学品

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历史批次信息供参考:

分析证书(COA)

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Experimental and computational studies of the structure and vibrational spectra of azetidine derivatives.

Thompson CA, et al.

Journal of Molecular Structure, 491(1), 67-80 (1999)

Phototransformations of azetidine radical cations stabilized in freonic matrices.

Sorokin ID, et al.

High Energy Chemistry, 48(3), 180-184 (2014)

Synthesis, 243-243 (2007)

Chemistry and pharmacology of nicotinic ligands based on 6-[5-(azetidin-2-ylmethoxy)pyridin-3-yl]hex-5-yn-1-ol (AMOP-H-OH) for possible use in depression.

Alan P Kozikowski et al.

ChemMedChem, 4(8), 1279-1291 (2009-07-02)

AMOP-H-OH (sazetidine-A; 6-[5-(azetidin-2-ylmethoxy)pyridin-3-yl]hex-5-yn-1-ol) and some sulfur-bearing analogues were tested for their activities in vitro against human alpha4beta2-, alpha4beta4-, alpha3beta4*- and alpha1*-nicotinic acetylcholine receptors (nAChRs). AMOP-H-OH was also assessed in an antidepressant efficacy model. AMOP-H-OH and some of its analogues have

Asymmetric synthesis of α,β-diamino acid derivatives with an aziridine-, azetidine- and γ-lactone-skeleton via Mannich-type additions across α-chloro-N-sulfinylimines.

Gert Callebaut et al.

Organic & biomolecular chemistry, 10(11), 2326-2338 (2012-02-09)

The efficient asymmetric synthesis of new chiral γ-chloro-α,β-diamino acid derivatives via highly diastereoselective Mannich-type reactions of N-(diphenylmethylene) glycine esters across a chiral α-chloro-N-p-toluenesulfinylimine was developed. The influence of the base, LDA or LiHMDS, used for the formation of the glycine

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全球贸易项目编号

货号	GTIN
281069-250MG	04061826214602
281069-1G	04061838135223

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