28115
巴豆基氯
technical, (cis+trans), mixture of cis- and trans-isomers (~1:6), ~70% (GC)
别名:
1-氯-2-丁烯（顺反异构体混合物）
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关于此项目
线性分子式:
CH3CH=CHCH2Cl
化学文摘社编号:
分子量:
90.55
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
209-739-5
Beilstein/REAXYS Number:
605304
MDL number:
Assay:
~70% (GC)
Form:
liquid
InChI key
YTKRILODNOEEPX-NSCUHMNNSA-N
InChI
1S/C4H7Cl/c1-2-3-4-5/h2-3H,4H2,1H3/b3-2+
SMILES string
C\C=C\CCl
grade
technical
assay
~70% (GC)
form
liquid
impurities
~30% 3-chloro-1-butene
refractive index
n20/D 1.430
bp
85-86 °C (lit.)
solubility
water: soluble 14 g/L at 20 °C
density
0.923 g/mL at 20 °C (lit.)
functional group
alkyl halide, chloro
Quality Level
General description
Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salts to give the corresponding allyltrichlorosilanes.
Application
Crotyl chloride has been used:
- to investihgate the kinetics of the reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K, to probe structure-reactivity relationships
- in the preparation of (E)-crotyltrichlorosilane
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Skin Sens. 1
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
10.4 °F - closed cup
flash_point_c
-12 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Stereohomogeneous synthesis of (E)-and (Z)-crotyltrifluorosilanes and highly stereoselective allylation of aldehydes.
Kira M, et al.
Tetrahedron Letters, 30(9), 1099-1102 (1989)
The condensation reaction of trichlorosilane with allylic chlorides catalyzed by copper salts in the presence of a tertiary amine.
Furuya N and Sukawa T.
Journal of Organometallic Chemistry, 96(1), C1-C3 (1975)
Rate constants for the reactions of chlorine atoms with a series of unsaturated aldehydes and ketones at 298 K: structure and reactivity.
Wang W, et al.
Physical Chemistry Chemical Physics, 4(10), 1824-1831 (2002)
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