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28115

巴豆基氯

Name: 巴豆基氯
Brand: ALDRICH

technical, (cis+trans), mixture of cis- and trans-isomers (~1:6), ~70% (GC)

别名:

1-氯-2-丁烯（顺反异构体混合物）

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关于此项目

线性分子式:

CH₃CH=CHCH₂Cl

化学文摘社编号:

591-97-9

分子量:

90.55

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

57648288

EC Number:

209-739-5

Beilstein/REAXYS Number:

605304

MDL number:

MFCD00000987

Assay:

~70% (GC)

Form:

liquid

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属性

Quality Level

100

grade

technical

assay

~70% (GC)

form

liquid

impurities

~30% 3-chloro-1-butene

refractive index

n20/D 1.430

bp

85-86 °C (lit.)

solubility

water: soluble 14 g/L at 20 °C

density

0.923 g/mL at 20 °C (lit.)

functional group

alkyl halide, chloro

SMILES string

C\C=C\CCl

InChI

1S/C4H7Cl/c1-2-3-4-5/h2-3H,4H2,1H3/b3-2+

InChI key

YTKRILODNOEEPX-NSCUHMNNSA-N

说明

General description

Crotyl chloride reacts with trichlorosilane in the presence of tertiary amine and copper salts to give the corresponding allyltrichlorosilanes.

Application

Crotyl chloride has been used:

to investihgate the kinetics of the reactions of atomic chlorine with series of unsaturated aldehydes and ketones at 298K, to probe structure-reactivity relationships
in the preparation of (E)-crotyltrichlorosilane

pictograms

GHS02,GHS06,GHS05

signalword

Danger

hcodes

H225,H301,H314,H317,H412

pcodes

P210 - P273 - P280 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A - Skin Sens. 1

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

10.4 °F - closed cup

flash_point_c

-12 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

法规信息

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分析证书(COA)

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Stereohomogeneous synthesis of (E)-and (Z)-crotyltrifluorosilanes and highly stereoselective allylation of aldehydes.

Kira M, et al.

Tetrahedron Letters, 30(9), 1099-1102 (1989)

Rate constants for the reactions of chlorine atoms with a series of unsaturated aldehydes and ketones at 298 K: structure and reactivity.

Wang W, et al.

Physical Chemistry Chemical Physics, 4(10), 1824-1831 (2002)

The condensation reaction of trichlorosilane with allylic chlorides catalyzed by copper salts in the presence of a tertiary amine.

Furuya N and Sukawa T.

Journal of Organometallic Chemistry, 96(1), C1-C3 (1975)

全球贸易项目编号

货号	GTIN
28115-100ML	04061837865220