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281573

(S)-(−)-1-氨基-2-(甲氧甲基)四氢吡咯

Name: (<I>S</I>)-(−)-1-氨基-2-(甲氧甲基)四氢吡咯
Brand: ALDRICH

95%

别名:

SAMP

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关于此项目

经验公式（希尔记法）:

C₆H₁₄N₂O

化学文摘社编号:

59983-39-0

分子量:

130.19

UNSPSC Code:

12352005

NACRES:

NA.22

PubChem Substance ID:

24856982

MDL number:

MFCD00064485

Beilstein/REAXYS Number:

1523794

Assay:

95%

Form:

liquid

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属性

assay

95%

form

liquid

optical activity

[α]20/D −79°, neat

optical purity

ee: 97% (GLC)

refractive index

n20/D 1.465 (lit.)

bp

42 °C/1.8 mmHg (lit.)

density

0.97 g/mL at 25 °C (lit.)

functional group

ether

SMILES string

COC[C@@H]1CCCN1N

InChI

1S/C6H14N2O/c1-9-5-6-3-2-4-8(6)7/h6H,2-5,7H2,1H3/t6-/m0/s1

InChI key

BWSIKGOGLDNQBZ-LURJTMIESA-N

说明

Application

(S)-(-)-1-氨基-2-(甲氧甲基)吡咯烷可作为手性辅助剂，用于(S)-2-乙基己酸和(S)-2-n-丙基-4-戊烯酸的不对称合成。在溴化锌存在下，与(E)-链烯基-环己基磺酸盐发生1,4加成反应以形成β-肼基-环己基磺酸盐。

与羰基化合物发生缩合反应，生成水合腙，后者在高度对映选择性合成中是有用的合成物。

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

161.6 °F - closed cup

flash_point_c

72 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

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Purification and Characterization of a Secretory Alkaline Metalloprotease with Highly Potent Antiviral Activity from Serratia marcescens Strain S3.

Yuanxia Qin et al.

Journal of agricultural and food chemistry, 67(11), 3168-3178 (2019-02-26)

In this study we report a secretory protein that was purified from Serratia marcescens strain S3 isolated from soil from the tobacco rhizosphere. Subsequent mass spectrometry and annotation characterized the protein as secretory alkaline metalloprotease (SAMP). SAMP plays a crucial

Synlett, 897-897 (1992)

Epithelial-specific Toll-like Receptor (TLR)5 Activation Mediates Barrier Dysfunction in Experimental Ileitis.

Loris R Lopetuso et al.

Inflammatory bowel diseases, 23(3), 392-403 (2017-02-02)

A large body of evidence supports a central role of TLR5 and its natural ligand, flagellin, in Crohn's disease (CD), with the precise mechanism(s) still unresolved. We investigated the role of flagellin/TLR5 in SAMP1/YitFc (SAMP) mice, a spontaneous model of

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货号	GTIN
281573-1G	04061826225578