281573
(S)-(−)-1-氨基-2-(甲氧甲基)四氢吡咯
95%
别名:
SAMP
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关于此项目
经验公式(希尔记法):
C6H14N2O
化学文摘社编号:
分子量:
130.19
Beilstein:
1523794
MDL编号:
UNSPSC代码:
12352005
PubChem化学物质编号:
NACRES:
NA.22
方案
95%
表单
liquid
旋光性
[α]20/D −79°, neat
光学纯度
ee: 97% (GLC)
折射率
n20/D 1.465 (lit.)
沸点
42 °C/1.8 mmHg (lit.)
密度
0.97 g/mL at 25 °C (lit.)
官能团
ether
SMILES字符串
COC[C@@H]1CCCN1N
InChI
1S/C6H14N2O/c1-9-5-6-3-2-4-8(6)7/h6H,2-5,7H2,1H3/t6-/m0/s1
InChI key
BWSIKGOGLDNQBZ-LURJTMIESA-N
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应用
(S)-(-)-1-氨基-2-(甲氧甲基)吡咯烷可作为手性辅助剂,用于(S)-2-乙基己酸和(S)-2-n-丙基-4-戊烯酸的不对称合成。在溴化锌存在下,与(E)-链烯基-环己基磺酸盐发生1,4加成反应以形成β-肼基-环己基磺酸盐。
与羰基化合物发生缩合反应,生成水合腙,后者在高度对映选择性合成中是有用的合成物。
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
161.6 °F - closed cup
闪点(°C)
72 °C - closed cup
个人防护装备
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Yuanxia Qin et al.
Journal of agricultural and food chemistry, 67(11), 3168-3178 (2019-02-26)
In this study we report a secretory protein that was purified from Serratia marcescens strain S3 isolated from soil from the tobacco rhizosphere. Subsequent mass spectrometry and annotation characterized the protein as secretory alkaline metalloprotease (SAMP). SAMP plays a crucial
Synlett, 897-897 (1992)
Tetrahedron, 49, 1821-1821 (1993)
Ludovica F Buttó et al.
Inflammatory bowel diseases, 25(1), 14-26 (2018-10-09)
TNF-like cytokine 1A (TL1A) and its functional receptor, death-domain-receptor-3 (DR3), are multifunctional mediators of effector and regulatory immunity. We aimed to evaluate the functional role and therapeutic potential of TL1A/DR3 signaling in Crohn's disease-like ileitis. Ileitis-prone SAMP1/YitFc (SAMP) and TNFΔARE/+
Nathaniel W Holton et al.
American journal of physiology. Cell physiology, 318(6), C1294-C1304 (2020-04-30)
The serotonin transporter (SERT) functions to regulate the availability of serotonin (5-HT) in the brain and intestine. An intestine-specific mRNA variant arising from a unique transcription start site and alternative promoter in the SERT gene has been identified (iSERT; spanning
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