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Merck
CN

282286

1,4-二碘四氟苯

98%

别名:

1,2,4,5-四氟-3,6-二碘苯, 1,4-二碘-2,3,5,6-四氟苯, 3,6-二碘-1,2,4,5-四氟苯, 四氟-1,4-二碘苯, 对二碘全氟苯

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关于此项目

经验公式(希尔记法):
C6F4I2
化学文摘社编号:
分子量:
401.87
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
206-877-8
MDL number:
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产品名称

1,4-二碘四氟苯, 98%

InChI key

VIXRAZODEODOJF-UHFFFAOYSA-N

InChI

1S/C6F4I2/c7-1-2(8)6(12)4(10)3(9)5(1)11

SMILES string

Fc1c(F)c(I)c(F)c(F)c1I

assay

98%

mp

108-110 °C (lit.)

functional group

fluoro
iodo

Quality Level

Application

1,4-二碘四氟苯在与多环芳烃的磷光共晶制备过程中用作卤素键供体

General description

1,4-二碘四氟苯与两分子烷氧基苯乙烯基吡啶形成三聚物复合物,作为新型卤键液晶元。已报道在90K下对4,4′-二吡啶-N,N′-二氧化物与1,4-二碘四氟苯形成的卤键复合物进行的电子密度研究

1,4-二碘四氟苯是一种双异位全氟碘苯,用于卤代吡啶盐的共晶化。

pictograms

Exclamation mark

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Halogen and hydrogen bond motifs in ionic cocrystals derived from 3-halopyridinium halogenides and perfluorinated iodobenzenes
Lidija P et al.
Crystal Growth & Design, 21, 6044-6050 (2021)
Jay Quentin et al.
Molecules (Basel, Switzerland), 25(4) (2020-02-23)
The halogen-bond (X-bond) donors 1,3- and 1,4-diiodotetrafluorobenzene (1,3-di-I-tFb and 1,4-di-I-tFb, respectively) form cocrystals with trans-1,2-bis(2-pyridyl)ethylene (2,2'-bpe) assembled by N···I X-bonds. In each cocrystal, 2(1,3-di-I-tFb)·2(2,2'-bpe) and (1,4-di-I-tFb)·(2,2'-bpe), the donor molecules support the C=C bonds of 2,2'-bpe to undergo an intermolecular [2+2]
Jiehao Fu et al.
iScience, 23(3), 100965-100965 (2020-03-22)
Here we introduce a σ-hole-containing volatile solid additive, 1, 4-diiodotetrafluorobenzene (A3), in PM6:Y6-based OSCs. Aside from the appropriate volatility of A3 additive, the synergetic halogen interactions between A3 and photoactive matrix contribute to more condensed and ordered molecular arrangement in
Mesogenic, trimeric, halogen-bonded complexes from alkoxystilbazoles and 1, 4-diiodotetrafluorobenzene.
<BIG>Bruce DW, et al. </BIG>
New. J. Chem., 32(3), 477-482 (2008)
Phosphorescent co-crystal assembled by 1, 4-diiodotetrafluorobenzene with carbazole based on C-Ip halogen bonding.
<BIG>Gao HY, et al. </BIG>
Journal of Materials Chemistry, 22(12), 5336-5343 (2012)

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