283096
叔戊基甲基醚
97%
别名:
1,1-二甲基丙基甲醚, TAME, 甲基2-甲基-2-丁醚, 甲基叔戊醚
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线性分子式:
C2H5C(CH3)2OCH3
化学文摘社编号:
分子量:
102.17
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-611-4
Beilstein/REAXYS Number:
1731452
MDL number:
Assay:
97%
Form:
liquid
InChI key
HVZJRWJGKQPSFL-UHFFFAOYSA-N
InChI
1S/C6H14O/c1-5-6(2,3)7-4/h5H2,1-4H3
SMILES string
CCC(C)(C)OC
assay
97%
form
liquid
Quality Level
refractive index
n20/D 1.3896
bp
85-86 °C (lit.)
density
0.76-0.78 g/mL at 25 °C (lit.)
functional group
ether
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General description
叔戊基甲基醚是一种含氧醚燃料，其在水中的含量已通过膜萃取离子迁移率光谱法进行定量。叔戊基甲基醚也称为2-甲氧基-2-甲基丁烷。已经研究了离子交换树脂（Amberlyst 18）催化的 叔戊基甲基醚反应的动力学。
Application
- 汽油含氧化合物叔戊基甲基醚（TAME）的环境危害鉴定。：研究评估了与使用叔戊基甲基醚（TAME）作为汽油含氧化合物相关的环境风险。重点介绍了对环境和人类健康的潜在危害，强调了对燃料中TAME使用进行仔细评估和监管的必要性。（Huttunen et al., 1997）。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Flam. Liq. 2 - STOT SE 3
target_organs
Central nervous system
存储类别
3 - Flammable liquids
wgk
WGK 1
flash_point_f
19.4 °F - closed cup
flash_point_c
-7 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Sanna Holopainen et al.
Talanta, 106, 448-453 (2013-04-20)
Fuel oxygenates are environmentally detrimental compounds due to their rapid migration to groundwater. Fuel oxygenates have been reported to cause taste and odour problems in drinking water, and they also have long-term health effects. Feasible analytical methods are required to
Kinetics of heterogeneously catalyzed tert-amyl methyl ether reactions in the liquid phase.
Rihko LK and Krause AOI.
Industrial & Engineering Chemistry Research, 34(4), 1172-1180 (1995)
R W Tyl et al.
Journal of applied toxicology : JAT, 23(6), 397-410 (2003-11-25)
Under Office of Prevention, Pesticides and Toxic Substances draft guidelines, CD weanling F0 rats (30 of each gender per group) inhaled tertiary amyl methyl ether vapor at 0, 250, 1500 or 3000 ppm 5 days a week and 6 h
James E Landmeyer et al.
Ground water, 48(1), 30-41 (2009-08-12)
Groundwater contamination by fuel-related compounds such as the fuel oxygenates methyl tert-butyl ether (MTBE), tert-butyl alcohol (TBA), and tert-amyl methyl ether (TAME) presents a significant issue to managers and consumers of groundwater and surface water that receives groundwater discharge. Four
Jessica Purswani et al.
Environmental toxicology and chemistry, 27(11), 2296-2303 (2008-06-05)
Nine bacterial strains isolated from two hydrocarbon-contaminated soils were selected because of their capacity for growth in culture media amended with 200 mg/L of one of the following gasoline oxygenates: Methyl-tert-butyl ether (MTBE), ethyl-tert-butyl ether (ETBE), and tert-amyl methyl ether
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