287717
硼烷氨复合物
technical grade, 90%
别名:
硼烷氨
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线性分子式:
H3N · BH3
化学文摘社编号:
分子量:
30.87
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
26111700
MDL number:
Assay:
90%
Form:
solid
产品名称
硼烷氨复合物, technical grade, 90%
InChI
1S/BH3.H3N/h2*1H3
SMILES string
B.N
InChI key
WZMUUWMLOCZETI-UHFFFAOYSA-N
grade
technical grade
assay
90%
form
solid
reaction suitability
reagent type: reductant
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Application
在质子或非质子介质中，硼吖嗪是一种温和、高效和立体选择性的醛和酮还原剂。 它可以作为储存介质，用于释放氢。硼吖嗪常用作形成六方氮化硼单层的硼烷氨（AB）来源，六方氮化硼单层可用作石墨烯生长基质。
General description
我们致力于为您提供更环保的替代产品，以符合“绿色化学的12项原则”的一项或多项原则要求。该产品为增强型，提高了能源效率。点击此处，查看更多详情。
硼烷-氨络合物是一种新型材料，其中氨通过其所有四个原子紧密结合到配体上。它是通过从路易斯碱(NH3)到路易斯酸(BH3)的电子提供而形成的接受体配合物。其呈现的B-N键距为1.564Å。
硼烷氨，也称为硼吖嗪，具有高氢含量（约20％质量）。在350-410K温度范围内，硼烷氨可发生热分解，伴随氢释放和放热。未来,它有可能用作燃料电池的氢源。
存储类别
11 - Combustible Solids
wgk
WGK 3
ppe
Eyeshields, Gloves
William C Ewing et al.
Journal of the American Chemical Society, 133(42), 17093-17099 (2011-10-04)
Studies of the activating effect of Verkade's base, 2,8,9-triisobutyl-2,5,8,9-tetraaza-1-phosphabicyclo[3.3.3]undecane (VB), on the rate and extent of H(2) release from ammonia borane (AB) have led to the syntheses and structural characterizations of three anionic aminoborane chain-growth products that provide direct support
X. Yang, et al.,
Tetrahedron, 67, 7121-7127 (2011)
Weng, B.; et al.
International Journal of Hydrogen Energy, 36, 10870-10870 (2011)
Thermal decomposition of B-N-H compounds investigated by using combined thermoanalytical methods.
Baitalow F, et al.
Thermochimica Acta, 391(1), 159-168 (2002)
Gang Hee Han et al.
ACS nano, 7(11), 10129-10138 (2013-11-05)
Graphene-boron nitride monolayer heterostructures contain adjacent electrically active and insulating regions in a continuous, single-atom thick layer. To date structures were grown at low pressure, resulting in irregular shapes and edge direction, so studies of the graphene-boron nitride interface were
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