287784
(1R,2R,3S,5R)-(-)-蒎烷二醇
99%
别名:
(-)-2-羟基异松蒎醇, [1R-(1α,2α,3α,5α)]-2,6,6-三甲基双环[3.3.1]庚烷-2,3-二醇
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关于此项目
经验公式（希尔记法）:
C10H18O2
化学文摘社编号:
分子量:
170.25
Beilstein:
2039144
MDL编号:
UNSPSC代码:
12352001
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
99%
旋光性
[α]21/D −8.6°, c = 6.5 in toluene
光学纯度
ee: 97% (GLC)
沸点
101-102 °C/1 mmHg (lit.)
mp
57-59 °C (lit.)
官能团
hydroxyl
SMILES字符串
CC1(C)[C@H]2C[C@H](O)[C@](C)(O)[C@@H]1C2
InChI
1S/C10H18O2/c1-9(2)6-4-7(9)10(3,12)8(11)5-6/h6-8,11-12H,4-5H2,1-3H3/t6-,7-,8+,10-/m1/s1
InChI key
MOILFCKRQFQVFS-BDNRQGISSA-N
应用
用于制备手性双烯丙基化试剂。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
230.0 °F - closed cup
闪点(°C)
110 °C - closed cup
个人防护装备
Eyeshields, Gloves, type N95 (US)
Simple, stable, and versatile double-allylation reagents for the stereoselective preparation of skeletally diverse compounds.
Feng Peng et al.
Journal of the American Chemical Society, 129(11), 3070-3071 (2007-02-24)
Gerald I Richard et al.
Applied spectroscopy, 62(5), 476-480 (2008-05-24)
The spectroscopic properties of a chiral boronic acid based resorcinarene macrocycle employed for chiral analysis were investigated. Specifically, the emission and excitation characteristics of tetraarylboronate resorcinarene macrocycle (TBRM) and its quantum yield were evaluated. The chiral selector TBRM was investigated
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