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287822

三(邻甲基苯基)膦

Name: 三(邻甲基苯基)膦
Brand: ALDRICH

97%

别名:

P(o-tol)₃, 三(2-甲苯基)膦

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关于此项目

线性分子式:

(CH₃C₆H₄)₃P

化学文摘社编号:

6163-58-2

分子量:

304.37

UNSPSC Code:

12352128

NACRES:

NA.22

PubChem Substance ID:

24857295

EC Number:

228-193-9

Beilstein/REAXYS Number:

661212

MDL number:

MFCD00008514

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属性

Quality Level

200

assay

97%

reaction suitability

reaction type: Cross Couplings, reaction type: Silylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Stille Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

123-125 °C (lit.)

functional group

phosphine

SMILES string

Cc1ccccc1P(c2ccccc2C)c3ccccc3C

InChI

1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3

InChI key

COIOYMYWGDAQPM-UHFFFAOYSA-N

说明

General description

三(对甲苯基)膦是一种配体，用于丙烷基碳酸酯的heck反应和suzuki 偶联。

Application

用于钌催化下醇直接胺化的配体。

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存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Accelerate catalyst and ligand screening with Catalexis integrated with BayBE™ for fast, cost-effective reaction optimization across benchtop and HTE workflows.

利用Catalexis进行数字反应优化

通过将 Catalexis 与 BayBE™ 集成，加速催化剂和配体的筛选，从而在台式和 HTE 工作流程中实现快速、经济高效的反应优化。

Phosphine Ligand Application Guide

Tuneable Emission of Polyhedral Oligomeric Silsesquioxane Based Nanostructures that Self-Assemble in the Presence of Europium(III) Ions: Reversible trans-to-cis Isomerization.

Valerio Cinà et al.

ChemPlusChem, 85(3), 391-398 (2020-03-03)

Hybrid nanostructures with switchable and reversible "blue-red-green" emission were efficiently synthesized. These nanostructures comprise polyhedral oligomeric silsesquioxanes (POSS) that behave as a nanocage that can be functionalized with terpyridine-based organic ligands, which can be easily complexed with europium (III) ions.

Bioinspired Polymer Nanocomposites Exhibit Giant Energy Density and High Efficiency at High Temperature.

Wenhan Xu et al.

Small (Weinheim an der Bergstrasse, Germany), 15(28), e1901582-e1901582 (2019-05-16)

Polymer dielectrics are ubiquitous in advanced electric energy storage systems. However, the relatively low operating temperature significantly menaces their widespread application at high temperatures, such as for hybrid vehicles and aerospace power electronics. Spider silk, a natural nanocomposite comprised of

Facilely Synthesized spiro[fluorene-9,9'-phenanthren-10'-one] in Donor-Acceptor-Donor Hole-Transporting Materials for Perovskite Solar Cells.

Yih-Chun Chen et al.

ChemSusChem, 11(18), 3225-3233 (2018-07-08)

We have demonstrated two novel donor-acceptor-donor (D-A-D) hole-transport material (HTM) with spiro[fluorene-9,9'-phenanthren-10'-one] as the core structure, which can be synthesized through a low-cost process in high yield. Compared to the incorporation of the conventional HTM of commonly used 2,2',7,7'-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene (Spiro-OMeTAD)

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全球贸易项目编号

货号	GTIN
287822-10G	04061826273234
287822-1G	04061826273241