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Merck
CN

287822

三(邻甲基苯基)膦

97%

别名:

P(o-tol)3, 三(2-甲苯基)膦

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关于此项目

线性分子式:
(CH3C6H4)3P
化学文摘社编号:
6163-58-2
分子量:
304.37
Beilstein:
661212
EC 号:
228-193-9
MDL编号:
MFCD00008514
UNSPSC代码:
12352128
PubChem化学物质编号:
24857295
NACRES:
NA.22

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质量水平

200

方案

97%

反应适用性

reaction type: Cross Couplings
reaction type: Silylations
reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reagent type: ligand
reaction type: Heck Reaction
reagent type: ligand
reaction type: Negishi Coupling
reagent type: ligand
reaction type: Stille Coupling
reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

123-125 °C (lit.)

官能团

phosphine

SMILES字符串

Cc1ccccc1P(c2ccccc2C)c3ccccc3C

InChI

1S/C21H21P/c1-16-10-4-7-13-19(16)22(20-14-8-5-11-17(20)2)21-15-9-6-12-18(21)3/h4-15H,1-3H3

InChI key

COIOYMYWGDAQPM-UHFFFAOYSA-N

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相关类别

一般描述

三(对甲苯基)膦是一种配体，用于丙烷基碳酸酯的heck反应和suzuki 偶联。

应用

用于钌催化下醇直接胺化的配体。

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
0000509186
0000509186
0000465411
0000465410
0000465411

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Yih-Chun Chen et al.
ChemSusChem, 11(18), 3225-3233 (2018-07-08)
We have demonstrated two novel donor-acceptor-donor (D-A-D) hole-transport material (HTM) with spiro[fluorene-9,9'-phenanthren-10'-one] as the core structure, which can be synthesized through a low-cost process in high yield. Compared to the incorporation of the conventional HTM of commonly used 2,2',7,7'-tetrakis[N,N-di(4-methoxyphenyl)amino]-9,9'-spirobifluorene (Spiro-OMeTAD)
Wenhan Xu et al.
Small (Weinheim an der Bergstrasse, Germany), 15(28), e1901582-e1901582 (2019-05-16)
Polymer dielectrics are ubiquitous in advanced electric energy storage systems. However, the relatively low operating temperature significantly menaces their widespread application at high temperatures, such as for hybrid vehicles and aerospace power electronics. Spider silk, a natural nanocomposite comprised of
Tri (o-tolyl) phosphine for highly efficient Suzuki coupling of propargylic carbonates with boronic acids
Junzhe X et al.
Chemical Communications (Cambridge, England), 54, 10451-10454 (2018)
Majken Borup Thomsen et al.
Molecular imaging and biology, 22(5), 1290-1300 (2020-06-10)
Loss of neuronal synapse function is associated with a number of brain disorders. The [11C]UCB-J positron emission tomography (PET) tracer allows for in vivo examination of synaptic density, as it binds to synaptic vesicle glycoprotein 2A (SV2A) expressed in presynaptic
Tetrahedron Letters, 47, 8881-8881 (2006)
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