Merck
CN

28910

Sigma-Aldrich

1,4-环己二烯

purum, ≥97.0% (GC)

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别名:
1,4-二氢苯
Empirical Formula (Hill Notation):
C6H8
CAS号:
分子量:
80.13
Beilstein:
1900733
EC 号:
MDL编号:
PubChem化学物质编号:
NACRES:
NA.22

等级

purum

质量水平

检测方案

≥97.0% (GC)

形式

liquid

包含

~0.2% 2,6-di-tert-butyl-4-methylphenol as stabilizer

折射率

n20/D 1.472 (lit.)
n20/D 1.473

bp

88-89 °C (lit.)

密度

0.847 g/mL at 25 °C (lit.)

SMILES string

C1C=CCC=C1

InChI

1S/C6H8/c1-2-4-6-5-3-1/h1-2,5-6H,3-4H2

InChI key

UVJHQYIOXKWHFD-UHFFFAOYSA-N

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此商品
216151125415C100005
1,4-Cyclohexadiene purum, ≥97.0% (GC)

Sigma-Aldrich

28910

1,4-环己二烯

1,4-Cyclohexadiene 97%

Sigma-Aldrich

125415

1,4-环己二烯

1,3-Cyclohexadiene contains 0.05% BHT as inhibitor, 97%

Sigma-Aldrich

C100005

1,3-环己二烯

form

liquid

form

liquid

form

liquid

form

liquid

refractive index

n20/D 1.472 (lit.), n20/D 1.473

refractive index

n20/D 1.475 (lit.)

refractive index

n20/D 1.472 (lit.)

refractive index

n20/D 1.474 (lit.)

bp

88-89 °C (lit.)

bp

148-150 °C (lit.)

bp

88-89 °C (lit.)

bp

80 °C (lit.)

density

0.847 g/mL at 25 °C (lit.)

density

0.94 g/mL at 25 °C (lit.)

density

0.847 g/mL at 25 °C (lit.)

density

0.841 g/mL at 25 °C (lit.)

grade

purum

grade

-

grade

-

grade

-

一般描述

1,4-Cyclohexadiene is an effective hydrogen donor for catalytic hydrogenation reaction. The interaction between graphene segments and 1,4-cyclohexadiene was stuided using density-functional tight-binding (DFTB) method.

应用

1,4-Cyclohexadiene (1,4-CHD) was used to study the formation of parent ion from heavy fragmentation of 1,4-CHD on irradiation with a high-intensity laser pulse.

其他说明

通过催化氢转移反应,在苄醚存在下选择性裂解苄酯

象形图

FlameHealth hazard

警示用语:

Danger

危险分类

Carc. 1A - Flam. Liq. 2 - Muta. 1B - STOT RE 2

靶器官

Blood

储存分类代码

3 - Flammable liquids

WGK

WGK 3

闪点(°F)

19.4 °F - closed cup

闪点(°C)

-7 °C - closed cup

个人防护装备

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品

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A.M. Felix et al.
The Journal of Organic Chemistry, 43, 4194-4194 (1978)
A key factor in parent and fragment ion formation on irradiation with an intense femtosecond laser pulse.
Chemical Physics Letters, 563-570 null
Rapid removal of protecting groups from peptides by catalytic transfer hydrogenation with 1, 4-cyclohexadiene.
The Journal of Organic Chemistry, 43(21), 4194-4196 (1978)
Yan Meng et al.
Nanoscale, 5(24), 12178-12184 (2013-09-24)
To promote possible applications of graphene in molecular identification based on stacking effects, in particular in recognizing aromatic amino acids and even sequencing nucleobases in life sciences, we comprehensively study the interaction between graphene segments and different cyclic organic hydrocarbons
Vladimir S Petrović et al.
Physical review letters, 108(25), 253006-253006 (2012-09-26)
We report the first study of UV-induced photoisomerization probed via core ionization by an x-ray laser. We investigated x-ray ionization and fragmentation of the cyclohexadiene-hexatriene system at 850 eV during the ring opening. We find that the ion-fragmentation patterns evolve

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