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290572

三(五氟苯基)膦

Name: 三(五氟苯基)膦
Brand: ALDRICH

97%, solid

别名:

Tris(perfluorophenyl)phosphine

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关于此项目

线性分子式:

(C₆F₅)₃P

化学文摘社编号:

1259-35-4

分子量:

532.14

NACRES:

NA.22

PubChem Substance ID:

24857475

UNSPSC Code:

12352101

EC Number:

215-021-2

MDL number:

MFCD00079654

Beilstein/REAXYS Number:

773243

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属性

产品名称

三(五氟苯基)膦, 97%

Quality Level

200

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

mp

108-110 °C (lit.)

functional group

phosphine

SMILES string

Fc1c(F)c(F)c(P(c2c(F)c(F)c(F)c(F)c2F)c3c(F)c(F)c(F)c(F)c3F)c(F)c1F

InChI

1S/C18F15P/c19-1-4(22)10(28)16(11(29)5(1)23)34(17-12(30)6(24)2(20)7(25)13(17)31)18-14(32)8(26)3(21)9(27)15(18)33

InChI key

FQLSDFNKTNBQLC-UHFFFAOYSA-N

说明

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Accelerate catalyst and ligand screening with Catalexis integrated with BayBE™ for fast, cost-effective reaction optimization across benchtop and HTE workflows.

利用Catalexis进行数字反应优化

通过将 Catalexis 与 BayBE™ 集成，加速催化剂和配体的筛选，从而在台式和 HTE 工作流程中实现快速、经济高效的反应优化。

Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates.

Barbara Chiavarino et al.

European journal of mass spectrometry (Chichester, England), 16(3), 407-414 (2008-01-01)

Functional models of the Compound I intermediate of monooxygenase heme enzymes, namely [(TPFPP)(*+)Fe(IV)=O](+) and [(TPFPP)Mn(V)=O](+) (TPFPP = meso-tetrakis (pentafluorophenyl)porphyrinato dianion), are obtained as bare species by electrospray ionization from solutions of appropriate precursors and their reactivity is investigated in the

Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species.

Rui Zhang et al.

Journal of the American Chemical Society, 127(18), 6573-6582 (2005-05-05)

Porphyrin-manganese(V)-oxo and porphyrin-manganese(IV)-oxo species were produced in organic solvents by laser flash photolysis (LFP) of the corresponding porphyrin-manganese(III) perchlorate and chlorate complexes, respectively, permitting direct kinetic studies. The porphyrin systems studied were 5,10,15,20-tetraphenylporphyrin (TPP), 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin (TPFPP), and 5,10,15,20-tetrakis(4-methylpyridinium)porphyrin (TMPyP). The

Structure of tris(pentafluorophenyl)phosphine.

A Karipides et al.

Acta crystallographica. Section C, Crystal structure communications, 45 ( Pt 11), 1743-1745 (1989-11-15)

C18F15P, Mr = 532.1, monoclinic, P2(1)/c, a = 7.194 (2), b = 17.930 (4), c = 13.834 (2) A, beta = 94.29 (2) degrees, V = 1779 A3, Z = 4, Dm = 2.00, Dx = 1.99 g cm-3, lambda(Mo

全球贸易项目编号

货号	GTIN
290572-1G	04061826303498