三(五氟苯基)膦

Name: 三(五氟苯基)膦
Brand: ALDRICH

97%, solid

别名:

Tris(perfluorophenyl)phosphine

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线性分子式:

(C₆F₅)₃P

化学文摘社编号:

1259-35-4

分子量:

532.14

Beilstein:

773243

EC 号:

215-021-2

MDL编号:

MFCD00079654

UNSPSC代码:

12352101

PubChem化学物质编号:

24857475

NACRES:

NA.22

主要文件

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产品名称

三(五氟苯基)膦, 97%

质量水平

200

方案

97%

表单

solid

反应适用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand

mp

108-110 °C (lit.)

官能团

phosphine

SMILES字符串

Fc1c(F)c(F)c(P(c2c(F)c(F)c(F)c(F)c2F)c3c(F)c(F)c(F)c(F)c3F)c(F)c1F

InChI

1S/C18F15P/c19-1-4(22)10(28)16(11(29)5(1)23)34(17-12(30)6(24)2(20)7(25)13(17)31)18-14(32)8(26)3(21)9(27)15(18)33

InChI key

FQLSDFNKTNBQLC-UHFFFAOYSA-N

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象形图

GHS07

警示用语：

Warning

危险声明

H315,H319,H335

预防措施声明

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Structure of tris(pentafluorophenyl)phosphine.

A Karipides et al.

Acta crystallographica. Section C, Crystal structure communications, 45 ( Pt 11), 1743-1745 (1989-11-15)

C18F15P, Mr = 532.1, monoclinic, P2(1)/c, a = 7.194 (2), b = 17.930 (4), c = 13.834 (2) A, beta = 94.29 (2) degrees, V = 1779 A3, Z = 4, Dm = 2.00, Dx = 1.99 g cm-3, lambda(Mo

Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species.

Rui Zhang et al.

Journal of the American Chemical Society, 127(18), 6573-6582 (2005-05-05)

Porphyrin-manganese(V)-oxo and porphyrin-manganese(IV)-oxo species were produced in organic solvents by laser flash photolysis (LFP) of the corresponding porphyrin-manganese(III) perchlorate and chlorate complexes, respectively, permitting direct kinetic studies. The porphyrin systems studied were 5,10,15,20-tetraphenylporphyrin (TPP), 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin (TPFPP), and 5,10,15,20-tetrakis(4-methylpyridinium)porphyrin (TMPyP). The

Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates.

Barbara Chiavarino et al.

European journal of mass spectrometry (Chichester, England), 16(3), 407-414 (2008-01-01)

Functional models of the Compound I intermediate of monooxygenase heme enzymes, namely [(TPFPP)(*+)Fe(IV)=O](+) and [(TPFPP)Mn(V)=O](+) (TPFPP = meso-tetrakis (pentafluorophenyl)porphyrinato dianion), are obtained as bare species by electrospray ionization from solutions of appropriate precursors and their reactivity is investigated in the

三(五氟苯基)膦

97%, solid

选择尺寸

关于此项目

主要文件

属性

产品名称

质量水平

方案

表单

反应适用性

mp

官能团

SMILES字符串

InChI

InChI key

相关类别

安全信息

象形图

警示用语：

危险声明

预防措施声明

危险分类

靶器官

储存分类代码

WGK

闪点(°F)

闪点(°C)

个人防护装备

文件

分析证书(COA)

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