三(五氟苯基)膦

Name: 三(五氟苯基)膦
Brand: ALDRICH

97%, solid

别名:

Tris(perfluorophenyl)phosphine

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线性分子式:

(C₆F₅)₃P

化学文摘社编号:

1259-35-4

分子量:

532.14

NACRES:

NA.22

PubChem Substance ID:

24857475

UNSPSC Code:

12352101

EC Number:

215-021-2

MDL number:

MFCD00079654

Beilstein/REAXYS Number:

773243

主要文件

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产品名称

三(五氟苯基)膦, 97%

InChI key

FQLSDFNKTNBQLC-UHFFFAOYSA-N

InChI

1S/C18F15P/c19-1-4(22)10(28)16(11(29)5(1)23)34(17-12(30)6(24)2(20)7(25)13(17)31)18-14(32)8(26)3(21)9(27)15(18)33

SMILES string

Fc1c(F)c(F)c(P(c2c(F)c(F)c(F)c(F)c2F)c3c(F)c(F)c(F)c(F)c3F)c(F)c1F

assay

97%

form

solid

reaction suitability

reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Heck Reaction, reaction type: Hiyama Coupling, reaction type: Negishi Coupling, reaction type: Sonogashira Coupling, reaction type: Stille Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: ligand

mp

108-110 °C (lit.)

functional group

phosphine

Quality Level

200

pictograms

GHS07

signalword

Warning

hcodes

H315,H319,H335

pcodes

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

历史批次信息供参考:

分析证书(COA)

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Laser flash photolysis generation and kinetic studies of porphyrin-manganese-oxo intermediates. Rate constants for oxidations effected by porphyrin-Mn(V)-oxo species and apparent disproportionation equilibrium constants for porphyrin-Mn(IV)-oxo species.

Rui Zhang et al.

Journal of the American Chemical Society, 127(18), 6573-6582 (2005-05-05)

Porphyrin-manganese(V)-oxo and porphyrin-manganese(IV)-oxo species were produced in organic solvents by laser flash photolysis (LFP) of the corresponding porphyrin-manganese(III) perchlorate and chlorate complexes, respectively, permitting direct kinetic studies. The porphyrin systems studied were 5,10,15,20-tetraphenylporphyrin (TPP), 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin (TPFPP), and 5,10,15,20-tetrakis(4-methylpyridinium)porphyrin (TMPyP). The

Probing bare high-valent transition oxo-metal complexes: an electrospray ionization Fourier transform ion cyclotron resonance study of reactive intermediates.

Barbara Chiavarino et al.

European journal of mass spectrometry (Chichester, England), 16(3), 407-414 (2008-01-01)

Functional models of the Compound I intermediate of monooxygenase heme enzymes, namely [(TPFPP)(*+)Fe(IV)=O](+) and [(TPFPP)Mn(V)=O](+) (TPFPP = meso-tetrakis (pentafluorophenyl)porphyrinato dianion), are obtained as bare species by electrospray ionization from solutions of appropriate precursors and their reactivity is investigated in the

Structure of tris(pentafluorophenyl)phosphine.

A Karipides et al.

Acta crystallographica. Section C, Crystal structure communications, 45 ( Pt 11), 1743-1745 (1989-11-15)

C18F15P, Mr = 532.1, monoclinic, P2(1)/c, a = 7.194 (2), b = 17.930 (4), c = 13.834 (2) A, beta = 94.29 (2) degrees, V = 1779 A3, Z = 4, Dm = 2.00, Dx = 1.99 g cm-3, lambda(Mo

三(五氟苯基)膦

97%, solid

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关于此项目

主要文件

属性

产品名称

InChI key

InChI

SMILES string

assay

form

reaction suitability

mp

functional group

Quality Level

相关类别

安全信息

pictograms

signalword

hcodes

pcodes

Hazard Classifications

target_organs

存储类别

wgk

flash_point_f

flash_point_c

ppe

文件

分析证书(COA)

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