292087
1-氯-2-丙醇
70%
别名:
氯丙醇, 丙氯仲醇
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关于此项目
线性分子式:
CH3CH(OH)CH2Cl+CH3CHClCH2OH
化学文摘社编号:
分子量:
94.54
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-819-6
Beilstein/REAXYS Number:
773653
MDL number:
Assay:
70%
InChI key
YYTSGNJTASLUOY-UHFFFAOYSA-N
InChI
1S/C3H7ClO/c1-3(5)2-4/h3,5H,2H2,1H3
SMILES string
CC(O)CCl
assay
70%
impurities
<25% 2-chloro-1-propanol
Quality Level
bp
126-127 °C (lit.)
density
1.111 g/mL at 25 °C (lit.)
functional group
chloro, hydroxyl
General description
1-氯-2-丙醇是通过红球菌属菌株DTB在 内消旋 - 双 -（1-氯-2-丙基）醚的降解过程中形成的中间体 。
Application
1-氯-2-丙醇用作：
- 环氧丙烷制作用化学中间体，即聚氨酯多元醇和丙二醇生产的起始物料
- 在用气体烯烃进行α、β-卤代醇酶促合成过程中作为α、β-卤代醇标准品
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
125.6 °F - closed cup
flash_point_c
52 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
J Geigert et al.
Applied and environmental microbiology, 45(2), 366-374 (1983-02-01)
The enzymatic synthesis of alpha,beta-halohydrins from gaseous alkenes is described. The enzymatic reaction required an alkene, a halide ion, dilute hydrogen peroxide, and a haloperoxidase enzyme. A wide range of gaseous alkenes were suitable for this reaction, including those containing
Leif-Alexander Garbe et al.
FEMS microbiology ecology, 55(1), 113-121 (2006-01-20)
Rhodococcus sp. strain DTB (DSM 44534) was grown on a mixture of (R,R)-, (S,S)- and meso-bis-(1-chloro-2-propyl) ether (BCPE) as the sole source of carbon and energy. During BCPE degradation 1'-chloro-2'-propyl-3-chloro-2-prop-1-enyl-ether (DVE), 1-chloro-2-propanol and chloroacetone intermediates were formed. The BCPE or
Propylene chlorohydrins: toxicology, metabolism, and environmental fate.
R S Yang
Reviews of environmental contamination and toxicology, 99, 47-59 (1987-01-01)
J A Bond et al.
Toxicology and applied pharmacology, 95(3), 444-455 (1988-09-30)
Propylene chlorohydrins, of which 1-chloro-2-propanol (1-CP) is a constituent, used as intermediates in the manufacture of propylene oxide and have been identified as potential air pollutants. The objective of these studies was to determine whether changes in the inhaled exposure
A R Jones et al.
Xenobiotica; the fate of foreign compounds in biological systems, 10(11), 835-846 (1980-11-01)
1. The metabolism of 1,2-dichloropropane in the rat has been investigated. The major urinary metabolite has been isolated and identified as N-acetyl-S-(2-hydroxypropyl)cysteine. Two minor metabolites of 1,2-dichloropropane have been identified as beta-chlorolactate and N-acetyl-S-(2,3-dihydroxypropyl)cysteine. 2. The fate of 1-chloro-2-hydroxypropane, a
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