292087
1-氯-2-丙醇
70%
别名:
氯丙醇, 丙氯仲醇
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关于此项目
线性分子式:
CH3CH(OH)CH2Cl+CH3CHClCH2OH
化学文摘社编号:
分子量:
94.54
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
204-819-6
Beilstein/REAXYS Number:
773653
MDL number:
产品名称
1-氯-2-丙醇, 70%
InChI key
YYTSGNJTASLUOY-UHFFFAOYSA-N
InChI
1S/C3H7ClO/c1-3(5)2-4/h3,5H,2H2,1H3
SMILES string
CC(O)CCl
assay
70%
impurities
<25% 2-chloro-1-propanol
refractive index
n20/D 1.439 (lit.)
bp
126-127 °C (lit.)
density
1.111 g/mL at 25 °C (lit.)
functional group
chloro
hydroxyl
Quality Level
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General description
1-氯-2-丙醇是通过红球菌属菌株DTB在 内消旋 - 双 -（1-氯-2-丙基）醚的降解过程中形成的中间体 。
Application
1-氯-2-丙醇用作：
- 环氧丙烷制作用化学中间体，即聚氨酯多元醇和丙二醇生产的起始物料
- 在用气体烯烃进行α、β-卤代醇酶促合成过程中作为α、β-卤代醇标准品
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
125.6 °F - closed cup
flash_point_c
52 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
J Geigert et al.
Applied and environmental microbiology, 45(2), 366-374 (1983-02-01)
The enzymatic synthesis of alpha,beta-halohydrins from gaseous alkenes is described. The enzymatic reaction required an alkene, a halide ion, dilute hydrogen peroxide, and a haloperoxidase enzyme. A wide range of gaseous alkenes were suitable for this reaction, including those containing
Leif-Alexander Garbe et al.
FEMS microbiology ecology, 55(1), 113-121 (2006-01-20)
Rhodococcus sp. strain DTB (DSM 44534) was grown on a mixture of (R,R)-, (S,S)- and meso-bis-(1-chloro-2-propyl) ether (BCPE) as the sole source of carbon and energy. During BCPE degradation 1'-chloro-2'-propyl-3-chloro-2-prop-1-enyl-ether (DVE), 1-chloro-2-propanol and chloroacetone intermediates were formed. The BCPE or
R W Biles et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 3(1), 27-33 (1983-01-01)
A 72:25 mixture of 1-chloro-2-propanol and 2-chloro-1-propanol was tested for genetic activity in a battery of short term tests. Chloropropanol was tested over a dose range of 527-167,250 micrograms/plate in the Salmonella/mammalian microsome mutagenicity assay. A dose dependent mutagenic response
A R Jones et al.
Xenobiotica; the fate of foreign compounds in biological systems, 10(11), 835-846 (1980-11-01)
1. The metabolism of 1,2-dichloropropane in the rat has been investigated. The major urinary metabolite has been isolated and identified as N-acetyl-S-(2-hydroxypropyl)cysteine. Two minor metabolites of 1,2-dichloropropane have been identified as beta-chlorolactate and N-acetyl-S-(2,3-dihydroxypropyl)cysteine. 2. The fate of 1-chloro-2-hydroxypropane, a
Reproductive toxicology. 1-Chloro-2-propanol.
Environmental health perspectives, 105 Suppl 1, 291-292 (1997-02-01)
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