293474
4-溴-2-氟苯甲醚
97%
别名:
4-溴-2-氟-1-甲氧基苯
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关于此项目
线性分子式:
BrC6H3(F)OCH3
化学文摘社编号:
分子量:
205.02
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
219-096-2
MDL number:
Assay:
97%
InChI key
DWNXGZBXFDNKOR-UHFFFAOYSA-N
InChI
1S/C7H6BrFO/c1-10-7-3-2-5(8)4-6(7)9/h2-4H,1H3
SMILES string
COc1ccc(Br)cc1F
assay
97%
refractive index
n20/D 1.545 (lit.)
bp
84 °C/7 mmHg (lit.)
density
1.59 g/mL at 25 °C (lit.)
functional group
bromo, fluoro
General description
The IR and FT-IR spectra of 4-bromo-2-fluoroanisole have been investigated.
Application
4-Bromo-2-fluoroanisole has been used in the synthesis of:
- 1,4-bis[(3′-fluoro-4′-n alkoxyphenyl)ethynyl]benzenes with n=1-12
- 7-fluoro-6-methoxy-1-methyl-2-naphthaldehyde
- 5,7-difluoro-6-methoxy-1-methyl-2-naphthaldehyde
- liquid crystals with terminal difluoromethoxy group and backbone of phenylbicyclohexane
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Vibrational spectra, first hyperpolarizability, HOMO-LUMO analysis of 4-bromo 2-fluro anisole.
Arivazhagan M, et al.
Indian Journal of Pure and Applied Physics, 50(5), 299-307 (2012)
Design of molecular architectures for polymeric mesophase formation.
Pugh C, et al.
Macromolecular Symposia, 98(1) (1995)
Syntheses of Phenylbicyclohexane Liquid Crystals with Terminal Difluoromethoxy Group [J].
Li J, et al.
Fine Chemicals / ????, 12, 004-004 (2004)
Rolf W Hartmann et al.
Journal of enzyme inhibition and medicinal chemistry, 19(2), 145-155 (2004-09-29)
Regioselectively fluorinated 1-(naphth-2-ylmethyl)imidazoles 1a-h have been synthesized starting from the corresponding (naphth-2-yl)methanols (2). 2a-d have been obtained by LiAlH4-promoted reduction of fluorinated 1-methyl-2-naphthaldehydes. The latter were easily prepared in fairly good overall yields by ceric ammonium nitrate (CAN)-promoted oxidative addition
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