InChI
1S/C7H11Cl/c8-7-4-5-1-2-6(7)3-5/h5-7H,1-4H2/t5-,6+,7?/m1/s1
SMILES string
ClC1C[C@@H]2CC[C@H]1C2
InChI key
PJWBUKHIZPKRJF-JEAXJGTLSA-N
assay
98%
refractive index
n20/D 1.4854 (lit.)
bp
66-66.5 °C/30 mmHg (lit.)
density
1.06 g/mL at 25 °C (lit.)
functional group
chloro
General description
exo-2-Chloronorbornane undergoes amination with trichloramine-aluminum chloride to yield 2-azabicyclo[3.2.1]octane, small amounts of the 3-isomer and exo-2-aminonorbornane.
Application
exo-2-Chloronorbornane has been employed as reagent during Friedel-Crafts alkylation of benzene and substituted benzenes with tin(IV) chloride or aluminium trichloride.
Aromatic substitution. 64. Friedel-Crafts Alkylation of Aromatics with exo-2-Chloro-and 7-Chloronorbornane.
Olah GA, et al.
The Journal of Organic Chemistry, 59(9), 2590-2593 (1994)
Amination of< i> exo</i>-2-chloronorbornane and norbornane with trichloramine-aluminum chloride.
Kovacic P, et al.
Tetrahedron, 26(2), 529-538 (1970)
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