294160
2-甲基氮丙啶
technical grade, 90%
别名:
丙烯亚胺
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经验公式（希尔记法）:
C3H7N
化学文摘社编号:
分子量:
57.09
EC Number:
200-878-7
UNSPSC Code:
12352100
PubChem Substance ID:
Beilstein/REAXYS Number:
102386
MDL number:
InChI key
OZDGMOYKSFPLSE-UHFFFAOYSA-N
InChI
1S/C3H7N/c1-3-2-4-3/h3-4H,2H2,1H3
SMILES string
CC1CN1
grade
technical grade
vapor pressure
140 mmHg ( 25 °C)
assay
90%
contains
sodium hydroxides as stabilizer
refractive index
n20/D 1.4125 (lit.)
bp
66-67 °C (lit.)
density
0.808 g/mL at 25 °C (lit.)
storage temp.
2-8°C
General description
2-Methylaziridine forms adduct with [60]fullerene, which on copolymerization with Novolac, Epon and Bisphenol A yields three dimensional polymers containing [60]fullerene with low coefficients of friction and good wear properties.
Application
2-Methylaziridine has been used in the synthesis of:
- new metallacycles and carbine complexes
- polyurethanes (thermoresponsive polymer) via copolymerization with supercritical CO2
signalword
Danger
Hazard Classifications
Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Corr. 1A
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
14.0 °F
flash_point_c
-10 °C
法规信息
新产品
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Barbara Klajnert et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 14(23), 7030-7041 (2008-06-26)
Maltose-modified poly(propylene imine) (PPI) dendrimers were synthesized by reductive amination of unmodified second- to fifth-generation PPI dendrimers in the presence of excess maltose. The dendrimers were characterized by using (1)H NMR, (13)C NMR, and IR spectroscopies; laser-induced liquid beam ionization/desorption
Addition and cycloaddition reactions of [Cp (CO) 2Re. tplbond. CTol]+ with cis-azoarenes, epoxides, 3, 3-dimethyloxetane, 2-methylaziridine, propylene sulfide, and benzophenone hydrazone. Displacement of the cyclopentadienyl ligand from the resultant metallacycles by trimethylphosphine.
Mercando LA, et al.
Organometallics, 12(5), 1559-1574 (1993)
Fabienne Grellepois et al.
Organic & biomolecular chemistry, 9(4), 1160-1168 (2010-12-16)
We report herein the synthesis of enantiomerically pure 2-phenyl- and 2-ethyl-2-trifluoromethylaziridines by Mitsunobu-type cyclisation of the corresponding N-protected amino alcohols, and our results regarding their ring opening with selected nucleophiles. Under basic conditions, N-tosyl aziridines have been regioselectively opened at
Marlies Fischer et al.
Biomacromolecules, 11(5), 1314-1325 (2010-04-22)
Accumulation of PrP(Sc), an insoluble and protease-resistant pathogenic isoform of the cellular prion protein (PrP(C)), is a hallmark in prion diseases. Branched polyamines, including PPI (poly(propylene imine)) dendrimers, are able to remove protease resistant PrP(Sc) and abolish infectivity, offering possible
E W Vogel et al.
Environmental and molecular mutagenesis, 29(2), 124-135 (1997-01-01)
We describe the consequences of a defect for nucleotide excision repair (NER) in oocytes for alkylation-induced mutagenesis in different germ-cell stages of Drosophila males. Mutant frequencies induced in NER+ condition (cross NER+female female x NER+male) were compared with those fixed
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