Quality Level
assay
98%
form
solid
mp
165-166 °C (lit.)
functional group
chloro
SMILES string
ClC12C[C@H]3C[C@H](C[C@H](C3)C1)C2
InChI
1S/C10H15Cl/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2/t7-,8+,9-,10-
InChI key
OZNXTQSXSHODFR-CHIWXEEVSA-N
General description
An unusual zwitterionic diradical intermediate complex was generated during the photoinduced electron-transfer substitution reaction between 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass.
Application
1-Chloroadamantane was employed as precursor for the synthesis of perfluoroadmantane derivatives via aerosol direct fluorination.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
此项目有
Aerosol fluorination of 1-chloroadamantane, 2-chloroadamantane, and methyl 1-adamantylacetate: a novel synthetic approach to 1-and 2-substituted hydryl-, methyl-, and (difluoromethyl-F-adamantanes.
Adcock JL, et al.
The Journal of Organic Chemistry, 57(17), 4749-4752 (1992)
Xue Li et al.
Journal of pharmaceutical sciences, 106(1), 395-401 (2016-11-07)
Supramolecular cyclodextrin-based nanoparticles (CD-NPs) mediated by host-guest interactions have gained increased popularity because of their "green" and simple preparation procedure, as well as their versatility in terms of inclusion of active molecules. Herein, we showed that original CD-NPs of around
John B Miller et al.
Journal of the American Chemical Society, 126(40), 12742-12743 (2004-10-08)
An unusual zwitterionic diradical intermediate complex R*...X-...HR'B*+ is generated during the photoinduced electron-transfer substitution reaction between alkyl halides (RX) and Lewis bases (HR'B). This reaction intermediate was observed for the 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass at 25
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 294861-5G | 04061826602997 |
| 294861-25G | 04061832674759 |