产品名称
1-氯金刚烷, 98%
InChI key
OZNXTQSXSHODFR-CHIWXEEVSA-N
InChI
1S/C10H15Cl/c11-10-4-7-1-8(5-10)3-9(2-7)6-10/h7-9H,1-6H2/t7-,8+,9-,10-
SMILES string
ClC12C[C@H]3C[C@H](C[C@H](C3)C1)C2
assay
98%
form
solid
mp
165-166 °C (lit.)
functional group
chloro
Quality Level
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Application
1-Chloroadamantane was employed as precursor for the synthesis of perfluoroadmantane derivatives via aerosol direct fluorination.
General description
An unusual zwitterionic diradical intermediate complex was generated during the photoinduced electron-transfer substitution reaction between 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
法规信息
新产品
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Xue Li et al.
Journal of pharmaceutical sciences, 106(1), 395-401 (2016-11-07)
Supramolecular cyclodextrin-based nanoparticles (CD-NPs) mediated by host-guest interactions have gained increased popularity because of their "green" and simple preparation procedure, as well as their versatility in terms of inclusion of active molecules. Herein, we showed that original CD-NPs of around
John B Miller et al.
Journal of the American Chemical Society, 126(40), 12742-12743 (2004-10-08)
An unusual zwitterionic diradical intermediate complex R*...X-...HR'B*+ is generated during the photoinduced electron-transfer substitution reaction between alkyl halides (RX) and Lewis bases (HR'B). This reaction intermediate was observed for the 1-chloroadamantane and tert-butylamine system in a hydrocarbon glass at 25
Aerosol fluorination of 1-chloroadamantane, 2-chloroadamantane, and methyl 1-adamantylacetate: a novel synthetic approach to 1-and 2-substituted hydryl-, methyl-, and (difluoromethyl-F-adamantanes.
Adcock JL, et al.
The Journal of Organic Chemistry, 57(17), 4749-4752 (1992)
Elena L Gromnitskaya et al.
Physical chemistry chemical physics : PCCP, 23(3), 2349-2354 (2021-01-16)
We present a comparative ultrasonic study of the elastic properties of adamantane and 1-chloroadamantane at high pressure (up to 1.4 GPa) and different temperatures (77-293 K) and at order-disorder transitions. The ultrasonic method provides complementary pictures of the order-disorder transitions
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