29510
(R)-(+)-(6,6′-二甲氧联苯-2,2′-二基)双(二苯基膦)
≥97%, optical purity ee: ≥99%
别名:
(R)-(+)-2,2′-双(二苯基膦)-6,6′-二甲氧-1,1′-联苯, (R)-(+)-MeO-BIPHEP, SL-A101-1
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About This Item
经验公式（希尔记法）:
C38H32O2P2
CAS Number:
分子量:
582.61
Beilstein:
4790083
MDL编号:
UNSPSC代码:
12352112
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
≥97%
光学纯度
ee: ≥99%
环保替代产品特性
Catalysis
Learn more about the Principles of Green Chemistry.
官能团
phosphine
环保替代产品分类
SMILES字符串
COc1cccc(P(c2ccccc2)c3ccccc3)c1-c4c(OC)cccc4P(c5ccccc5)c6ccccc6
InChI
1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3
InChI key
KRJVQCZJJSUHHO-UHFFFAOYSA-N
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一般描述
与 Solvias AG 联合销售
We are committed to bringing you Greener Alternative Products, which adhere to one of the four categories of Greener Alternatives. This product is a Biobased products, showing key improvements in Green Chemistry Principles “Less Hazardous Chemical Syntheses” and “Use of Renewable Feedstock”.
应用
Atropisomeric MeOBIPHEP ligands
- Hydrogenation of α- and β-functionalized ketones
- Hydrogenation of heteroarenes
- C–C coupling reactions
Atropisomeric diphosphine; the Rh(I) complex is employed for highly enantioselective asymmetric isomerization of allylamines to enamines; the Ru(II) complex hydrogenates ß-keto esters in high enantioselectivity; the Pd(0) complex for cyclization of hydroxy allylic carbonates.
Ligand for ruthenium-catalyzed greener amine synthesis by enamine reduction with hydrogen gas.
Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
Asymmetric Synthesis of (S)-3-Amino-4-methoxy-butan-1-ol by Way of Reductive Amination
包装
Bottomless glass bottle. Contents are inside inserted fused cone.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
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