应用
Cyclopropane has been used as the pseudo-π unsaturated hydrocarbon prototype to study the rotational spectrum of its complex formed with chlorine monofluoride and the similarity of this complex with isotopomers.
包装
Supplied in a Sure/Pac™ cylinder and has a brass needle valve with a male 1/4" NPTF outlet thread installed. Before using the cylinder, ensure that the valve is closed, then remove the galvanized steel hex cap that seals the outlet valve.
Compatible with the following:
Compatible with the following:
法律信息
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
警示用语:
Danger
危险声明
预防措施声明
危险分类
Flam. Gas 1 - Press. Gas Liquefied gas
储存分类代码
2A - Gases
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, multi-purpose combination respirator cartridge (US)
法规信息
新产品
此项目有
Pedro S Coelho et al.
Science (New York, N.Y.), 339(6117), 307-310 (2012-12-22)
Transition metal-catalyzed transfers of carbenes, nitrenes, and oxenes are powerful methods for functionalizing C=C and C-H bonds. Nature has evolved a diverse toolbox for oxene transfers, as exemplified by the myriad monooxygenation reactions catalyzed by cytochrome P450 enzymes. The isoelectronic
Shuhei Kawamura et al.
Journal of medicinal chemistry, 56(9), 3689-3700 (2013-04-04)
The natural product belactosin A (1) with a trans-cyclopropane structure is a useful prototype compound for developing potent proteasome (core particle, CP) inhibitors. To date, 1 and its analogues are the only CP ligands that bind to both the nonprimed
A pseudo-? analogue of a Mulliken b?. a? type complex: The rotational spectrum of cyclopropane?chlorine monofluoride.
Holloway JH & Legon AC.
J. Chem. Soc., Faraday Trans., 93(3), 373-378 (1997)
Enzymatic chemistry of cyclopropane, epoxide, and aziridine biosynthesis.
Christopher J Thibodeaux et al.
Chemical reviews, 112(3), 1681-1709 (2011-10-25)
Thomas Schalck et al.
Microorganisms, 9(2) (2021-02-04)
Fuels and polymer precursors are widely used in daily life and in many industrial processes. Although these compounds are mainly derived from petrol, bacteria and yeast can produce them in an environment-friendly way. However, these molecules exhibit toxic solvent properties
商品
Solvias MeOBIPHEP Ligands: State-of-the-art atropisomeric MeOBIPHEP ligands, also referred to as MeO-BIPHEP, originally developed by Roche, have an extraordinarily broad performance profile for many synthetic applications due to their modular ligand design.
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