296112
二乙基锌 溶液
1.0 M in hexanes
别名:
Zincdiethyl
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关于此项目
线性分子式:
(C2H5)2Zn
化学文摘社编号:
分子量:
123.51
UNSPSC Code:
12352103
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
3587207
产品名称
二乙基锌 溶液, 1.0 M in hexanes
InChI
1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
SMILES string
CC[Zn]CC
InChI key
HQWPLXHWEZZGKY-UHFFFAOYSA-N
concentration
1.0 M in hexanes
density
0.726 g/mL at 25 °C
Quality Level
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Application
二乙基锌溶液可作为试剂用于制备：
- 在Rh(I)催化下由α, β-不饱和酮类化合物制备α-三氟甲基酮类化合物。
- 用于交叉偶联反应的炔基锌试剂。
- 在樟脑衍生β-氨基醇的存在下由芳香族和脂肪族醛制备手性二级醇。
- 与α,β-不饱和酮共同制备1, 4共轭加成产物。
- 从醛和酮类化合物制备α-氟丙烯酸。
signalword
Danger
target_organs
Central nervous system, Nervous system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-9.4 °F - closed cup
flash_point_c
-23 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3 - Water-react. 1
法规信息
危险化学品
此项目有
Rhodium-Catalyzed Novel Trifluoromethylation at the α-Position of α, β-Unsaturated Ketones
Sato K, et al.
Organic Letters, 6(23), 4359-4361 (2004)
Enantioselective copper-catalyzed conjugate addition using chiral diaminocarbene ligands
Guillen F, et al.
Tetrahedron Asymmetry, 12(15), 2083-2086 (2001)
Novel and general cross-coupling reactions of alkynylzinc reagents and organotellurium compounds
Dabdoub MJ, et al.
Tetrahedron Letters, 41(4), 437-440 (2000)
Asymmetric addition of diethylzinc to aldehydes catalyzed by a camphor-derived β-amino alcohol
Wu Z-L, et al.
Tetrahedron Asymmetry, 20(13), 1556-1560 (2009)
Organic Syntheses, 83, 177-177 (2006)
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