Quality Level
concentration
1.0 M in hexanes
density
0.726 g/mL at 25 °C
SMILES string
CC[Zn]CC
InChI
1S/2C2H5.Zn/c2*1-2;/h2*1H2,2H3;
InChI key
HQWPLXHWEZZGKY-UHFFFAOYSA-N
Application
二乙基锌溶液可作为试剂用于制备：
- 在Rh(I)催化下由α, β-不饱和酮类化合物制备α-三氟甲基酮类化合物。
- 用于交叉偶联反应的炔基锌试剂。
- 在樟脑衍生β-氨基醇的存在下由芳香族和脂肪族醛制备手性二级醇。
- 与α,β-不饱和酮共同制备1, 4共轭加成产物。
- 从醛和酮类化合物制备α-氟丙烯酸。
Still not finding the right product?
Explore all of our products under 二乙基锌 溶液
signalword
Danger
target_organs
Central nervous system, Nervous system
supp_hazards
存储类别
4.2 - Pyrophoric and self-heating hazardous materials
wgk
WGK 3
flash_point_f
-9.4 °F - closed cup
flash_point_c
-23 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3 - Water-react. 1
法规信息
危险化学品
此项目有
Novel and general cross-coupling reactions of alkynylzinc reagents and organotellurium compounds
Dabdoub MJ, et al.
Tetrahedron Letters, 41(4), 437-440 (2000)
Enantioselective copper-catalyzed conjugate addition using chiral diaminocarbene ligands
Guillen F, et al.
Tetrahedron Asymmetry, 12(15), 2083-2086 (2001)
Asymmetric addition of diethylzinc to aldehydes catalyzed by a camphor-derived β-amino alcohol
Wu Z-L, et al.
Tetrahedron Asymmetry, 20(13), 1556-1560 (2009)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 296112-800ML | 04061826649336 |
| 296112-2L | 04061838119209 |
| 296112-PZ | 04061823822152 |
| 296112-100ML | 04061826649329 |