296643
(R)-(-)-仲丁胺
99%
别名:
(R)-(-)-2-氨基丁烷
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关于此项目
线性分子式:
C2H5CH(NH2)CH3
化学文摘社编号:
分子量:
73.14
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
EC Number:
236-232-6
Beilstein/REAXYS Number:
1718761
MDL number:
Assay:
99%
产品名称
(R)-(-)-仲丁胺, 99%
InChI key
BHRZNVHARXXAHW-SCSAIBSYSA-N
InChI
1S/C4H11N/c1-3-4(2)5/h4H,3,5H2,1-2H3/t4-/m1/s1
SMILES string
CC[C@@H](C)N
assay
99%
optical activity
[α]19/D −7.5°, neat
refractive index
n20/D 1.393 (lit.)
bp
63 °C (lit.)
density
0.72 g/mL at 25 °C (lit.)
functional group
amine
Quality Level
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Application
(R)-(−)-sec-Butylamine can be used:
- To prepare (R)-(−)-sec-butylbis(2-hydroxyethyl)amine, an intermediate for the synthesis of aminodiphosphine ligands.
- As a substrate to demonstrate the stereochemistry of Mitsunobu reaction in the synthesis of secondary amines.
- As a model compound in the study of singlet-triplet transitions in circular dichroism.
Packaging
Bottomless glass bottle. Contents are inside inserted fused cone.
signalword
Danger
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1A
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-2.2 °F - closed cup
flash_point_c
-19 °C - closed cup
ppe
Faceshields, Gloves, Goggles
法规信息
农药列管产品
危险化学品
此项目有
Synthesis of the New Chiral (R)-and (S)-Aminodiphosphine Ligands sec-Butylbis (2-(diphenylphosphino) ethyl) amine, sec-Butylbis (2-(dicyclohexylphosphino) ethyl) amine, and (alpha-Methylbenzyl) bis (2-(dicyclohexylphosphino) ethyl) amine and Their Organom
Bianchini C, et al.
Organometallics, 16(20), 4403-4414 (1997)
Stereospecific synthesis of secondary amines by the Mitsunobu reaction
Edwards ML, et al.
Tetrahedron Letters, 31(24), 3417-3420 (1990)
Detection of singlet-triplet transitions in circular dichroism. A study of 2-aminobutane
Basil A and Gedanken A
Journal of the American Chemical Society, 111(26), 9237-9238 (1989)
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