297054
三甲基硅甲基锂 溶液
1.0 M in pentane
别名:
三甲基硅甲基锂
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关于此项目
线性分子式:
(CH3)3SiCH2Li
化学文摘社编号:
分子量:
94.16
NACRES:
NA.22
UNSPSC Code:
12352103
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4123225
产品名称
三甲基硅甲基锂 溶液, 1.0 M in pentane
InChI
1S/C4H11Si.Li/c1-5(2,3)4;/h1H2,2-4H3;
SMILES string
[Li]C[Si](C)(C)C
InChI key
RJPBNMJOQNIBQW-UHFFFAOYSA-N
concentration
1.0 M in pentane
bp
35-36 °C
density
0.65 g/mL at 25 °C
storage temp.
2-8°C
Quality Level
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Application
启动环硅氧烷的聚合和共聚合反应。金属络合物的烷基化反应。
Packaging
25 mL 可靠/密封™瓶推荐为一次性使用瓶。重复穿刺可能导致产品性能下降。
Legal Information
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
signalword
Danger
hcodes
Hazard Classifications
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 3
flash_point_f
-56.2 °F - closed cup
flash_point_c
-49 °C - closed cup
ppe
Faceshields, Gloves, Goggles
法规信息
危险化学品
此项目有
Polym. Bull., 32, 35-35 (1994)
Journal of Organometallic Chemistry, 447, 51-51 (1993)
Xiaoyan Tang et al.
Nature communications, 9(1), 2345-2345 (2018-06-13)
Bacterial poly(3-hydroxybutyrate) (P3HB) is a perfectly isotactic, crystalline material possessing properties suitable for substituting petroleum plastics, but high costs and low volumes of its production are impractical for commodity applications. The chemical synthesis of P3HB via ring-opening polymerization (ROP) of
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