298352
(1S)-(-)-2,10-樟脑磺内酰胺
98%
别名:
(-)-10,2-樟脑磺内酰胺, (-)-exo-10,2-莰烷磺内酰胺, (1S,5R)-10,10-二甲基-3-硫杂-4-氮杂三环[5.2.1.01,5]癸烷-3,3-二氧化物, [3aS-(3aα,6α,7aβ)]-六氢-8,8-二甲基-3H-3a,6-亚甲基-2,1-苯并异噻唑基-2,2-二氧化物
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关于此项目
经验公式（希尔记法）:
C10H17NO2S
化学文摘社编号:
分子量:
215.31
UNSPSC Code:
12352005
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
83811
Quality Segment
assay
98%
form
solid
optical activity
[α]19/D −32°, c = 5 in chloroform
mp
181-183 °C (lit.)
SMILES string
[H][C@@]12CC[C@]3(CS(=O)(=O)N[C@@H]3C1)C2(C)C
InChI
1S/C10H17NO2S/c1-9(2)7-3-4-10(9)6-14(12,13)11-8(10)5-7/h7-8,11H,3-6H2,1-2H3/t7-,8-,10-/m1/s1
InChI key
DPJYJNYYDJOJNO-NQMVMOMDSA-N
General description
(1S,2R,4R)-(−)-2,10-Camphorsultam may be employed as a chiral probe for the optical resolution by HPLC and X-ray crystallographic determination of the absolute stereochemistry of carboxylic acids.
Application
(1S)-(−)-2,10-Camphorsultam may be used in the asymmetric synthesis of (S)- and (R)-N-Fmoc-S-trityl-α-methylcysteine. It may be used as proton source in the synthesis of chiral α,γ-substituted γ-butyrolactones.
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves