300721
二叔丁基硝基氧
technical grade, 90%
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关于此项目
线性分子式:
[(CH3)3C]2NO
化学文摘社编号:
分子量:
145.24
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352000
EC Number:
219-298-0
MDL number:
Assay:
90%
InChI key
CKJMHSMEPSUICM-UHFFFAOYSA-N
InChI
1S/C8H18NO/c1-7(2,3)9(10)8(4,5)6/h1-6H3
SMILES string
CC(C)(C)N([O])C(C)(C)C
grade
technical grade
assay
90%
refractive index
n20/D 1.435 (lit.)
bp
74-75 °C/34 mmHg (lit.)
functional group
amine
storage temp.
2-8°C
Application
二叔丁基氮氧化物（DTBN）可用作：
- 一种添加剂，用于通过使用铜基金属有机骨架（MOF）作为催化剂而将胺和二硫化物或硫醇进行氧化偶联以合成N-亚砜基亚胺。
- 可控自由基聚合反应中的引发剂。
- 一种试剂，通过与芳香酸氯化物发生以制备N-芳酰基-o-芳酰基-N-叔-丁基羟胺。
在室温下将初级和次级苄胺氧化成亚胺的试剂，还用于对 Zeolite X 中的 Lewis 酸中心进行 ESR 研究。
自旋标记物。一直用于对小鼠角质层中的脂质微区和热现象进行定位。
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
114.8 °F - closed cup
flash_point_c
46 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Limitations in the synthesis of high molecular weight polymers via nitroxide-mediated controlled radical polymerization: modeling studies
Kruse TM, et al.
Macromolecules, 36(20), 7812-7823 (2003)
The Journal of Organic Chemistry, 50, 5382-5382 (1985)
S J Rehfeld et al.
The Journal of investigative dermatology, 91(5), 499-505 (1988-11-01)
Lipids appear to play a critical role as regulators of stratum corneum desquamation. In this study, we observed discrete lipid phase transitions at physiologic temperatures in both normal human scale (NHS) and in lipid extracts of NHS by differential scanning
J Fuchs et al.
The Journal of investigative dermatology, 98(5), 713-719 (1992-05-01)
Electron paramagnetic resonance (EPR) is a spectroscopic technique that allows detection of paramagnetic compounds, e.g., free radicals, in skin, and is used for measuring skin membrane fluidity and polarity. EPR imaging is concerned with spatially resolved EPR spectroscopy. We studied
Heverton Silva Camargos et al.
Lipids, 45(5), 419-427 (2010-04-03)
In this work, we have used electron paramagnetic resonance (EPR) spectroscopy of the small spin label di-tert-butyl nitroxide (DTBN), which partitions the aqueous and hydrocarbon phases, to study the interaction of the terpenes alpha-terpineol, 1,8-cineole, L(-)-carvone and (+)-limonene with the
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