301035
羟基甲苯磺酰碘苯
96%
别名:
HTIB, Iodosobenzene-I-mono-p-toluenesulfonate, Koser 试剂, NSC 294176, [羟基（4-甲苯磺基）碘] 苯, 对甲苯磺酸盐, 羟基(甲苯磺酰氧代)碘苯, 羟基（苯基）碘甲苯磺酸盐
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关于此项目
线性分子式:
CH3C6H4SO3I(OH)C6H5
化学文摘社编号:
分子量:
392.21
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
2150074
Assay:
96%
产品名称
羟基甲苯磺酰碘苯, 96%
InChI
1S/C13H13IO4S/c1-11-7-9-13(10-8-11)19(16,17)18-14(15)12-5-3-2-4-6-12/h2-10,15H,1H3
SMILES string
Cc1ccc(cc1)S(=O)(=O)O[I](O)c2ccccc2
InChI key
LRIUKPUCKCECPT-UHFFFAOYSA-N
assay
96%
reaction suitability
reagent type: oxidant
mp
131-137 °C (lit.)
functional group
iodo
tosylate
Quality Level
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Application
广泛用于合成各种有机化合物的氧化剂。
用作以下过程的反应物：
- 无配体钯催化的 Heck 型偶联反应
- 硫脲脱氢制备碳二亚胺
- 醇、醛、胺氧化转化制备腈
- 芳香族醛肟反应制备取代苯胺
- 高烯丙基醇氧化环化合成四氢呋喃
- β-羟基酮肟氧化 N-O 偶联制备异恶唑啉 N-氧化物
- 氨肽酶抑制剂合成中的扩环反应
- 酸性条件下的氧化和质子化反应
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Kumar, R.
Synlett, 2764-2764 (2007)
S Tuuli Karhu et al.
Archives of toxicology (2018-07-11)
Safety assessment of drug candidates in numerous in vitro and experimental animal models is expensive, time consuming and animal intensive. More thorough toxicity profiling already in the early drug discovery projects using human cell models, which more closely resemble the
Damian Tarasek et al.
Bioorganic chemistry, 97, 103692-103692 (2020-03-11)
p-Diphenols, such as homogentisic acid, gentisic acid, etamsylate, and calcium dobesilate, interfere with diagnostic tests utilizing the Trinder reaction but the mechanisms of these effects are not fully understood. We observed substantial differences both in oxidation of p-diphenols by horseradish
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