301485
1-氯乙基氯甲酸酯
98%
别名:
ACE-Cl
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关于此项目
线性分子式:
CH3CHClOCOCl
化学文摘社编号:
分子量:
142.97
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
256-834-2
Beilstein/REAXYS Number:
1747601
MDL number:
Assay:
98%
Form:
liquid
General description
1-氯乙基氯甲酸酯可用作叔胺的选择性去烷化剂（dealkylating agent ）。
Application
氯甲酸 1-氯乙酯用于：
- 用于天然荧光毛细管电泳和激光诱导荧光检测测定生物体液中多种药物滥用时的 N-脱甲基反应
- 硅保护醇选择性脱硅的催化剂
- 作为 N -脱甲基叔胺中的试剂，生成用于法医毒理学应用的药物代谢产物引用物质
- 作为从胺中裂解二苯甲基的试剂
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
104.9 °F - closed cup
flash_point_c
40.5 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Efficient chemoselective deprotection of silyl ethers using catalytic 1-chloroethyl chloroformate in methanol.
Yeom C-E, et al.
Tetrahedron, 61(52), 12227-12237 (2005)
Efficient chemoselective deprotection of silyl ethers using catalytic 1-chloroethyl chloroformate in methanol
Yeom CE, et al.
Tetrahedron, 61(52), 12227-12237 (2005)
Preparation of< i> N</i>-demethylated drug metabolites for analytical purposes using 1-chloroethyl chloroformate.
Pelander A, et al.
Forensic Science International, 85(3), 193-198 (1997)
Tetrahedron, 62, 6869-6869 (2006)
Ahmed Alnajjar et al.
Electrophoresis, 25(10-11), 1592-1600 (2004-06-10)
Methods for separation and determination of multiple drugs of abuse in biological fluids using capillary electrophoresis (CE) with native fluorescence and laser-induced fluorescence (LIF) detection are described herein. Using native fluorescence, normorphine, morphine, 6-acetyl morphine (6-AM), and codeine were analyzed
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