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302015

5-己炔-1-醇

96%

别名:

1-己炔-6-醇, 1-羟基-5-己炔, 5-己炔醇, 5-己醇, 6-羟基-1-己炔

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关于此项目

线性分子式:
HC≡C(CH2)4OH
化学文摘社编号:
928-90-5
分子量:
98.14
MDL number:
MFCD00002980
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
24858225
Beilstein/REAXYS Number:
1739774
Assay:
96%
Form:
liquid
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Quality Level

100

assay

96%

form

liquid

refractive index

n20/D 1.450 (lit.)

bp

73-75 °C/15 mmHg (lit.)

density

0.89 g/mL at 25 °C (lit.)

functional group

hydroxyl

SMILES string

OCCCCC#C

InChI

1S/C6H10O/c1-2-3-4-5-6-7/h1,7H,3-6H2

InChI key

GOQJMMHTSOQIEI-UHFFFAOYSA-N

Application

5-己炔-1-醇被用于合成：
  • 肉桂醇稠环烯啶
  • llycopodium生物碱，(+)-nankakurine A以及(+)-nankakurine B
  • 7-苯甲酰氧基-3-(2-硝基苯硒基)-1,5-环十烷

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

158.0 °F - closed cup

flash_point_c

70 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKDB4060
MKCZ8094
MKCX7512
MKCW6223
MKCT9541

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商品

Functionalized Alkynes

Alkynes' versatility enables reactions like addition, metathesis, hydroboration, cleavage, coupling, and cycloadditions in synthetic chemistry.

Olga V Vinogradova et al.
The Journal of organic chemistry, 76(16), 6937-6941 (2011-07-02)
A short and efficient synthesis of cinnoline-fused cyclic enediyne is reported. Richter cyclization of o-(1,3-butadiynyl)phenyltriazene produced 3-alkynyl-4-bromocinnoline. The Sonogashira coupling of the latter with 5-hexyn-1-ol was employed for the introduction of a second acetylenic moiety. The crucial cyclization step was
Ryan A Altman et al.
The Journal of organic chemistry, 75(22), 7519-7534 (2010-10-21)
The first total syntheses of the Lycopodium alkaloids (+)-nankakurine A (2), (+)-nankakurine B (3), and the originally purported structure 1 of nankakurine A were accomplished. The syntheses of 2 and 3 feature a demanding intramolecular azomethine imine cycloaddition as the
M Michida et al.
Nucleic acids symposium series, (37)(37), 55-56 (1997-01-01)
7-Benzoyloxy-3-(2-nitrophenylseleno)-1,5-cyclodecadiyne (13) was prepared from 5-hexyn-1-ol and propargyl bromide via 10-iodo-7-(t-butyldiphenylsiloxy)-5,9-decadiynal (10). The facile cyclization of the acyclic precursor 10 would be rationalized in terms of "bulky group (TBDPSO) assisted conformational control". Oxidation of 13 by NaIO4, followed by thermal
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货号GTIN
302015-25G04061826665688
302015-1G04061826665671
302015-5G04061826665695