302147
(S)-(+)-2-甲氧基-2-苯乙醇
98%
别名:
β-甲氧基苯乙醇, (+)-β-甲氧基苯乙醇
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关于此项目
线性分子式:
C6H5CH(OCH3)CH2OH
化学文摘社编号:
分子量:
152.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352112
MDL number:
Assay:
98%
Form:
liquid
产品名称
(S)-(+)-2-甲氧基-2-苯乙醇, 98%
InChI
1S/C9H12O2/c1-11-9(7-10)8-5-3-2-4-6-8/h2-6,9-10H,7H2,1H3/t9-/m1/s1
SMILES string
CO[C@H](CO)c1ccccc1
InChI key
JDTUPLBMGDDPJS-SECBINFHSA-N
assay
98%
form
liquid
optical activity
[α]19/D +133°, c = 1 in acetone
optical purity
ee: 99% (GLC)
refractive index
n20/D 1.52 (lit.)
bp
65 °C/0.1 mmHg (lit.)
density
1.054 g/mL at 25 °C (lit.)
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Application
(S)-(+)-2-Methoxy-2-phenylethanol can be used:
- As a starting material for the synthesis of N-substituted 6,7-benzomorphan based opioid receptor agonists.
- As a ligand in the preparation of organolanthanoid complexes.
- As starting material for the synthesis of N-acetyl-O-((2S)-2-methoxy-2-phenylethyl)-L-serine, a serine proteases inhibitor.
signalword
Warning
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
208.4 °F - closed cup
flash_point_c
98 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Probing enzyme stereospecificity. Evaluation of β-alkoxy-α-amino acids with two stereocenters as inhibitors of serine proteases
Lee T and Jones JB
Tetrahedron, 51(27), 7331-7346 (1995)
Solid-state and solution structures of several new [LnCp′ 2 (OR)] 2 complexes (Ln= Pr, Yb) with chiral, oxygen-functionalized mu-alkoxide ligands
Steudel A, et al.
Journal of Organometallic Chemistry, 570(1), 89-96 (1998)
(2S)-N-2-methoxy-2-phenylethyl-6,7-benzomorphan compound (2S-LP2): Discovery of a biased mu/delta opioid receptor agonist
Pasquinucci L, et al.
European Journal of Medicinal Chemistry, 168, 189-198 (2019)
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