302163
(R)-(-)-1-苯基-1,2-乙二醇
99%
别名:
(-)-苯乙二醇, (R)-(-)-苯基乙二醇
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关于此项目
线性分子式:
HOCH2CH(C6H5)OH
化学文摘社编号:
分子量:
138.16
Beilstein:
2355547
MDL编号:
UNSPSC代码:
12352002
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
99%
旋光性
[α]20/D −69°, c = 1 in chloroform
沸点
272-274 °C (lit.)
mp
64-67 °C (lit.)
官能团
hydroxyl
phenyl
SMILES字符串
OC[C@H](O)c1ccccc1
InChI
1S/C8H10O2/c9-6-8(10)7-4-2-1-3-5-7/h1-5,8-10H,6H2/t8-/m0/s1
InChI key
PWMWNFMRSKOCEY-QMMMGPOBSA-N
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应用
合成不对称氢化反应的手性膦催化剂时所用的中间体。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
J. Chem. Soc. Perkin Trans. II, 489-489 (1982)
The Journal of Organic Chemistry, 44, 1729-1729 (1979)
Rongzhen Zhang et al.
Wei sheng wu xue bao = Acta microbiologica Sinica, 49(2), 204-209 (2009-05-19)
To prepare (S)-1-phenyl-1,2-ethanediol by a one-step method, we constructed an enzyme coupled system consisting of (R)- and (S)-specific carbonyl reductases in Escherichia coli. The genes coding (R)- and (S)-specific carbonyl reductases from Candida parapsilosis were inserted into a co-expression vector
Jin-Zhao Wang et al.
Biomedical chromatography : BMC, 21(5), 497-501 (2007-03-16)
A simple HPLC method for the simultaneous determination of phenylglyoxylic acid (PGA), mandelic acid (MA), styrene glycol (SG) and hippuric acid (HA) in cell culture medium was developed. Analysis was performed on a C(18) column with a mobile phase composed
Qingsen Hu et al.
Bioresource technology, 101(21), 8461-8463 (2010-06-25)
In this study, a highly efficient process for Candida parapsilosis-catalyzed deracemization of racemic 1-phenyl-1,2-ethanediol (PED) was described, based on a resin-based in situ substrate feeding and product removal (ISSFPR) methodology. The resin H103 was selected and used to keep the
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