302295
5-硝基噻吩-2-甲醛
98%
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关于此项目
经验公式（希尔记法）:
C5H3NO3S
化学文摘社编号:
分子量:
157.15
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
224-850-9
MDL number:
Assay:
98%
Form:
solid
产品名称
5-硝基噻吩-2-甲醛, 98%
InChI key
CHTSWZNXEKOLPM-UHFFFAOYSA-N
InChI
1S/C5H3NO3S/c7-3-4-1-2-5(10-4)6(8)9/h1-3H
SMILES string
[H]C(=O)c1ccc(s1)[N+]([O-])=O
assay
98%
form
solid
mp
75-77 °C (lit.)
solubility
acetone: soluble 1%, clear, yellow
functional group
aldehyde
nitro
Quality Level
Application
5-Nitro-2-thiophenecarboxaldehyde was used in preparation of 2, 3-dihydro-2-(5-nitro-2-thienyl) quinazolin-4-(1H)-ones and various novel oxime ether derivatives, anti-protozoan agents.
General description
Diastereoselectivity in [4+2] cycloaddition of 1-methoxy-2-methyl-3-(trimethylsiloxy)-1,3-pentadiene with 5-nitro-2-thiophenecarboxaldehyde was investigated.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Antibacterial 2,3-dihydro-2-(5-nitro-2-thienyl)-quinazolin-4(1H)-ones.
R J Alaimo et al.
Journal of medicinal chemistry, 15(3), 335-336 (1972-03-01)
Michael P Doyle et al.
Proceedings of the National Academy of Sciences of the United States of America, 101(15), 5391-5395 (2004-04-03)
Chiral dirhodium(II) carboxamidates are highly efficient catalysts for reactions between a variety of aldehydes and activated dienes. Catalyst loadings as low at 0.01 mol % have been realized with enantioselectivities up to 97%. Kinetic investigations reveal a pronounced electronic influence
Ali Almasirad et al.
Iranian journal of pharmaceutical research : IJPR, 10(4), 727-731 (2011-10-01)
A series of new 2-(phenylthio) benzoylarylhydrazones were synthesized by acid-catalyzed condensation of hydrazide 3 with corresponding aldehydes. The chemical structures of the compounds were elucidated by FT-IR, (1)H-NMR and Mass spectra. All newly synthesized compounds were evaluated for their antimycobacterial
Synthesis and< i> in vitro</i> anti-protozoan activity of new 5-nitrothiophene oxime ether derivatives.
Delmas F, et al.
European Journal of Medicinal Chemistry, 28(1), 23-27 (1993)
Jian Xu et al.
Food chemistry, 221, 1530-1538 (2016-12-17)
We synthesized a series of 4- or 5-functionalized TCT derivatives (1-12) and investigated their inhibitory activities and mechanisms on tyrosinase by using Spectrofluorimetry, 1H and 13C NMR titration and IR spectra. The results of the fluorescence spectra and NMR titrations
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