302325
2-氯乙烷磺酰氯
96%
别名:
2-氯-1-乙烷磺酰氯
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关于此项目
线性分子式:
ClCH2CH2SO2Cl
化学文摘社编号:
分子量:
163.02
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-594-1
Beilstein/REAXYS Number:
1751202
MDL number:
产品名称
2-氯乙烷磺酰氯, 96%
InChI key
VHCSBTPOPKFYIU-UHFFFAOYSA-N
InChI
1S/C2H4Cl2O2S/c3-1-2-7(4,5)6/h1-2H2
SMILES string
ClCCS(Cl)(=O)=O
vapor pressure
15 mmHg ( 84 °C)
assay
96%
form
liquid
refractive index
n20/D 1.493 (lit.)
bp
84-86 °C/15 mmHg (lit.)
density
1.56 g/mL at 25 °C (lit.)
functional group
chloro
Quality Level
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Application
将 2-氯乙烷磺酰氯用于一锅法磺酰化/分子内噻-迈克尔方案中，用于合成 1,5,2-二噻二氮杂 1,1-二氧化物。它也用于合成具有呋喃、碳环、半环或无环 1,3-二烯部分的乙烯基磺酰胺。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 1 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
>230.0 °F
flash_point_c
> 110 °C
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Qin Zang et al.
Heterocycles, 86(2), doi:10-doi:10 (2014-01-05)
A novel one-pot sulfonylation/intramolecular thia-Michael protocol is reported for the synthesis of 1,5,2-dithiazepine 1,1-dioxides. Sulfonylation between cysteine ethyl ester/cysteamine and 2-chloroethanesulfonyl chloride, followed by
Victor O Rogachev et al.
Nature protocols, 1(6), 3076-3087 (2007-04-05)
Vinylsulfonamides with a furan, carbocyclic, semicyclic or acyclic 1,3-diene moiety are synthetized via a domino elimination-amidation reaction of 2-chloroethanesulfonyl chloride. Intramolecular Diels-Alder reaction of these vinylsulfonamides with thermal (toluene, 110 degrees C) or high pressure (dichloromethane, 13 kbar) activation provides
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