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线性分子式:
CH3CO2CH2COCl
化学文摘社编号:
分子量:
136.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
237-542-4
MDL number:
Assay:
97%
Form:
liquid
产品名称
乙酰氧基乙酰氯, 97%
InChI key
HZDNNJABYXNPPV-UHFFFAOYSA-N
InChI
1S/C4H5ClO3/c1-3(6)8-2-4(5)7/h2H2,1H3
SMILES string
CC(=O)OCC(Cl)=O
assay
97%
form
liquid
refractive index
n20/D 1.428 (lit.)
bp
55 °C/12 mmHg (lit.)
density
1.27 g/mL at 25 °C (lit.)
functional group
acyl chloride
ester
Quality Level
Application
乙酰氧基乙酰氯用于合成稳定的螺-β-内酰胺类和甘酰基异羟肟酸的轴向和赤道构象。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
M D Corbett et al.
Chemical research in toxicology, 1(4), 222-227 (1988-07-01)
A new and improved method for the synthesis of glycolylhydroxamic acids is described. The two-step method involves acylation of arylhydroxylamines with acetoxyacetyl chloride, followed by saponification of the ester bond to give the desired products. The conversion of hydroxamic acids
Naveen Anand et al.
The Journal of organic chemistry, 76(15), 5999-6006 (2011-06-15)
The facile synthesis of the stabilized axial and equatorial conformers of spiro-β-lactams was achieved via entrapment of cyclohexanone imines (Schiff bases) with acetoxyacetyl chloride in a [2 + 2]-cycloaddition reaction followed by their kinetic resolution. The immobilization of the racemic
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