302368
乙酰氧基乙酰氯
97%
别名:
α-乙酰氧基乙酰氯, (乙酰氧基)乙酰氯, (氯羰基)甲基乙酸酯, 2-(乙酰氧基)乙酰氯, 2-乙酰氧基乙酰氯, 2-氯-2-氧代乙酸乙酯, 乙酰乙酰氯, 乙酸(氯羰基)甲酯
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关于此项目
线性分子式:
CH3CO2CH2COCl
化学文摘社编号:
分子量:
136.53
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
237-542-4
MDL number:
产品名称
乙酰氧基乙酰氯, 97%
InChI key
HZDNNJABYXNPPV-UHFFFAOYSA-N
InChI
1S/C4H5ClO3/c1-3(6)8-2-4(5)7/h2H2,1H3
SMILES string
CC(=O)OCC(Cl)=O
assay
97%
form
liquid
refractive index
n20/D 1.428 (lit.)
bp
55 °C/12 mmHg (lit.)
density
1.27 g/mL at 25 °C (lit.)
functional group
acyl chloride
ester
Quality Level
Application
乙酰氧基乙酰氯用于合成稳定的螺-β-内酰胺类和甘酰基异羟肟酸的轴向和赤道构象。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
supp_hazards
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Naveen Anand et al.
The Journal of organic chemistry, 76(15), 5999-6006 (2011-06-15)
The facile synthesis of the stabilized axial and equatorial conformers of spiro-β-lactams was achieved via entrapment of cyclohexanone imines (Schiff bases) with acetoxyacetyl chloride in a [2 + 2]-cycloaddition reaction followed by their kinetic resolution. The immobilization of the racemic
M D Corbett et al.
Chemical research in toxicology, 1(4), 222-227 (1988-07-01)
A new and improved method for the synthesis of glycolylhydroxamic acids is described. The two-step method involves acylation of arylhydroxylamines with acetoxyacetyl chloride, followed by saponification of the ester bond to give the desired products. The conversion of hydroxamic acids
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