Merck
CN
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文件

安全信息

303070

Sigma-Aldrich

五氟苯甲酸甲酯

99%

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线性分子式:
C6F5CO2CH3
CAS号:
36629-42-2
分子量:
226.10
MDL编号:
MFCD00012172
PubChem化学物质编号:
24858294

检测方案

99%

形式

liquid

折射率

n20/D 1.431 (lit.)

密度

1.532 g/mL at 25 °C (lit.)

SMILES string

COC(=O)c1c(F)c(F)c(F)c(F)c1F

InChI

1S/C8H3F5O2/c1-15-8(14)2-3(9)5(11)7(13)6(12)4(2)10/h1H3

InChI key

UXJRQNXHCZKHRJ-UHFFFAOYSA-N

相关类别

应用

Methyl pentafluorobenzoate was used in preparation of photocoupling agent, based on perfluorophenylazide (PFPA)-conjugated polyallylamine, for efficient immobilization of polymers, nanoparticles, graphene and small molecules. It was also used in preparation of photoactive reagent N-hydroxysuccinimide (NHS)-PFPA.

象形图

Exclamation mark
GHS07

警示用语：

Warning

危险声明

H315 - H319 - H335

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

10 - Combustible liquids

WGK

WGK 3

闪点(°F)

172.4 °F - closed cup

闪点(°C)

78 °C - closed cup

个人防护装备

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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Huibin Wang et al.
Bioconjugate chemistry, 22(1), 26-32 (2010-12-09)
A universal photochemical method has been established for the immobilization of intact carbohydrates and their analogues, and for the fabrication of carbohydrate microarrays. The method features the use of perfluorophenyl azide (PFPA)-modified substrates and the photochemical reaction of surface azido
Takuya Kubo et al.
Langmuir : the ACS journal of surfaces and colloids, 27(15), 9372-9378 (2011-06-28)
A highly efficient photocoupling agent, based on perfluorophenylazide (PFPA)-conjugated polyallylamine (PAAm), was developed for the efficient immobilization of polymers, nanoparticles, graphene, and small molecules. The conjugate, PAAm-PFPA, was synthesized, and the percentage of the photoactive moiety, PFPA, can be controlled
Hiroshi Kobayashi et al.
Scientific reports, 10(1), 13850-13850 (2020-08-17)
We report on a potential method to separate sugars by using the specific interaction between fullerenes and saccharides in liquid chromatography (LC). Aromatic rings with high electron density are believed to interact strongly with saccharides due to CH-π and/or OH-π
Marllyn Marques da Silva et al.
Regulatory toxicology and pharmacology : RTP, 103, 282-291 (2019-02-23)
The fibrinolytic enzyme produced by Mucor subtilissimus UCP 1262 was obtained by solid fermentation and purified by ion exchange chromatography using DEAE-Sephadex A50. The enzyme toxicity was evaluated using mammalian cell lineages: HEK-293, J774.A1, Sarcoma-180 and PBMCs which appeared to
Na Kong et al.
Carbohydrate research, 405, 33-38 (2015-03-10)
Carbohydrate-functionalized single-walled carbon nanotubes (SWNTs) were synthesized using microwave-assisted reaction of perfluorophenyl azide with the nanotubes. The results showed that microwave radiation provides a rapid and effective means to covalently attach carbohydrates to SWNTs, producing carbohydrate-SWNT conjugates for biorecognition. The

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