产品名称
环戊二烯化钠, 2.4 M in THF
form
liquid
Quality Segment
reaction suitability
reagent type: ligand
concentration
2.4 M in THF
density
0.938 g/mL at 25 °C
SMILES string
[Na]C1C=CC=C1
InChI
1S/C5H5.Na/c1-2-4-5-3-1;/h1-5H;
InChI key
PDTZVKVFAJGNRV-UHFFFAOYSA-N
Application
环戊二烯基钠可用作制备茂金属和环戊二烯基金属络合物的有用试剂。
也可用于以下物质的合成：
- 二茂钌和富勒烯分子杂交物, Ru(η5- C60Me5)( η5-C5H5) (松散二茂钌)。
- 通过钯催化的烯丙基烷基化作用生成烯丙基取代的环戊二烯。
- 双（环戊二烯基）二氯化锆，其可用作二吲哚甲烷合成和杂芳基烷基化的催化剂。
- 由二苯基膦炔烃和CoCl(PPh3)3生成Cp-cobaltacycle。
signalword
Danger
target_organs
Central nervous system, Respiratory system
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
flash_point_f
1.4 °F - closed cup
flash_point_c
-17 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
supp_hazards
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3 - Water-react. 1