306800
(R)-(+)-2-氯丙酸
99%
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关于此项目
线性分子式:
CH3CH(Cl)CO2H
化学文摘社编号:
分子量:
108.52
UNSPSC Code:
12352101
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1720258
Assay:
99%
Form:
liquid
InChI
1S/C3H5ClO2/c1-2(4)3(5)6/h2H,1H3,(H,5,6)/t2-/m1/s1
SMILES string
C[C@@H](Cl)C(O)=O
InChI key
GAWAYYRQGQZKCR-UWTATZPHSA-N
assay
99%
form
liquid
optical activity
[α]20/D +14°, neat
refractive index
n20/D 1.4345 (lit.)
bp
185-188 °C (lit.)
density
1.258 g/mL at 20 °C (lit.)
functional group
carboxylic acid, chloro
Quality Level
Application
(R)-(+)-2-Chloropropionic acid can be used as a starting material in the synthesis of:
- Thiolactic acid, a key intermediate, which is used for the preparation of 2(R),5(S)-oxathiolanones by reacting with pivalaldehyde.
- (R)-2-chloropropionyl chloride, a key intermediate, which is utilized in the synthesis of (R)-4,5-dihydro-5-methylpyridazin-3(2H)-one derivative with pyrazolopyridine ring as a potential phosphodiesterase inhibitor.
- 2-Chloropropionamide derivatives as protein disulfide isomerase (PID) inhibitors.
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
213.8 °F - closed cup
flash_point_c
101 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
A short and efficient synthesis of a chiral pyridazinone derivative by the chiral-pool method
Yoshida N, et al.
Synthesis, 2004(10), 1554-1556 (2004)
Dharmaraja Allimuthu et al.
ACS chemical biology, 12(8), 2124-2131 (2017-06-15)
Resurgent interest in covalent target engagement in drug discovery has demonstrated that small molecules containing weakly reactive electrophiles can be safe and effective therapies. Several recently FDA-approved drugs feature an acrylamide functionality to selectively engage cysteine side chains of kinases
Jill M McFadden et al.
Organic letters, 4(22), 3859-3862 (2003-02-26)
[formula: see text] A new and efficient asymmetric synthesis of naturally occurring (5R)-thiolactomycin (1) using D-alanine as the source of chirality is described.
Eugénie Grigorian et al.
Frontiers in microbiology, 12, 725997-725997 (2021-10-09)
L-2-halocid dehalogenases (L-2-HADs) have been mainly characterized from terrestrial polluted environments. By contrast, knowledge is still scarce about their role in detoxification of predominant halocarbons in marine environments. Here, phylogenetic analyses showed a wide diversity of homologous L-2-HADs, especially among
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