307882
(R)-(-)-2-苯甘氨酸甲酯 盐酸盐
≥95%
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关于此项目
线性分子式:
C6H5CH(NH2)CO2CH3·HCl
化学文摘社编号:
分子量:
201.65
PubChem Substance ID:
eCl@ss:
32160406
UNSPSC Code:
12352200
NACRES:
NA.22
EC Number:
243-399-9
MDL number:
assay
≥95%
form
solid
optical activity
[α]20/D −118°, c = 1 in H2O
reaction suitability
reaction type: solution phase peptide synthesis
mp
189-191 °C (lit.)
application(s)
peptide synthesis
SMILES string
Cl.COC(=O)[C@H](N)c1ccccc1
InChI
1S/C9H11NO2.ClH/c1-12-9(11)8(10)7-5-3-2-4-6-7;/h2-6,8H,10H2,1H3;1H/t8-;/m1./s1
InChI key
DTHMTBUWTGVEFG-DDWIOCJRSA-N
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Alessandro Moretto et al.
Chirality, 17(8), 481-487 (2005-08-23)
Reactions of a racemic amine with chiral, N(alpha)-acetylated, C(alpha)-methyl l-phenylglycine-based dipeptide 5(4H)-oxazolones proceed diastereoselectively to give predominantly dipeptide alkylamides comprising d-alpha-phenylethylamine. Diastereoselectivity is remarkably sensitive to solvent polarity and reaction temperature but not significantly to the nature of the C(alpha)-tetrasubstituted
Wei Du et al.
Biotechnology and applied biochemistry, 38(Pt 2), 107-110 (2003-05-17)
Ammonium, provided by ammonium carbamate as a novel acyl acceptor, was adopted for enzymic enantioselective ammonolysis of racemic phenylglycine methyl ester in this paper and it has been found that the reaction conditions have profound effects on enzymic activity and
Wei Du et al.
Sheng wu gong cheng xue bao = Chinese journal of biotechnology, 18(2), 242-245 (2002-08-01)
A novel reaction-enzymatic ammonolysis discovered in the mid of 1990s has been demonstrated to be a very promising alternative in the preparation of optically pure compounds. The effects of organic solvent, initial water activity, temperature and additives on lipase Novozym435-catalyzed
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 307882-100G | 04061832594262 |
| 307882-25G | 04061832594279 |