307882
(R)-(-)-2-苯甘氨酸甲酯 盐酸盐
≥95%
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关于此项目
线性分子式:
C6H5CH(NH2)CO2CH3·HCl
化学文摘社编号:
分子量:
201.65
PubChem Substance ID:
eCl@ss:
32160406
UNSPSC Code:
12352200
NACRES:
NA.22
EC Number:
243-399-9
MDL number:
产品名称
(R)-(-)-2-苯甘氨酸甲酯 盐酸盐, ≥95%
InChI key
DTHMTBUWTGVEFG-DDWIOCJRSA-N
InChI
1S/C9H11NO2.ClH/c1-12-9(11)8(10)7-5-3-2-4-6-7;/h2-6,8H,10H2,1H3;1H/t8-;/m1./s1
SMILES string
Cl.COC(=O)[C@H](N)c1ccccc1
assay
≥95%
form
solid
optical activity
[α]20/D −118°, c = 1 in H2O
reaction suitability
reaction type: solution phase peptide synthesis
mp
189-191 °C (lit.)
application(s)
peptide synthesis
signalword
Warning
hcodes
pcodes
Hazard Classifications
Eye Irrit. 2
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Alessandro Moretto et al.
Chirality, 17(8), 481-487 (2005-08-23)
Reactions of a racemic amine with chiral, N(alpha)-acetylated, C(alpha)-methyl l-phenylglycine-based dipeptide 5(4H)-oxazolones proceed diastereoselectively to give predominantly dipeptide alkylamides comprising d-alpha-phenylethylamine. Diastereoselectivity is remarkably sensitive to solvent polarity and reaction temperature but not significantly to the nature of the C(alpha)-tetrasubstituted
John W Van Klink et al.
Chirality, 16(8), 549-558 (2004-08-04)
Several Anisotome diterpene derivatives were synthesized in an attempt to obtain a crystalline compound for X-ray analysis. Although we were unable to obtain a suitable crystal, the absolute configuration of the irregular diterpene skeleton was determined using two other techniques:
Wei Du et al.
Sheng wu gong cheng xue bao = Chinese journal of biotechnology, 18(2), 242-245 (2002-08-01)
A novel reaction-enzymatic ammonolysis discovered in the mid of 1990s has been demonstrated to be a very promising alternative in the preparation of optically pure compounds. The effects of organic solvent, initial water activity, temperature and additives on lipase Novozym435-catalyzed
Wei Du et al.
Biotechnology and applied biochemistry, 38(Pt 2), 107-110 (2003-05-17)
Ammonium, provided by ammonium carbamate as a novel acyl acceptor, was adopted for enzymic enantioselective ammonolysis of racemic phenylglycine methyl ester in this paper and it has been found that the reaction conditions have profound effects on enzymic activity and
Life cycle assessment of a coupled solar photocatalytic-biological process for wastewater treatment.
Ivan Muñoz et al.
Water research, 40(19), 3533-3540 (2006-09-23)
A comparative life cycle assessment (LCA) of two solar-driven advanced oxidation processes, namely heterogeneous semiconductor photocatalysis and homogeneous photo-Fenton, both coupled to biological treatment, is carried out in order to identify the environmentally preferable alternative to treat industrial wastewaters containing
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