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Merck
CN

308323

顺均二苯代乙烯氧化物

97%

别名:

顺式-2,3-二苯基环氧乙烷

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经验公式(希尔记法):
C14H12O
化学文摘社编号:
分子量:
196.24
UNSPSC Code:
12162002
NACRES:
NA.23
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
82737
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InChI

1S/C14H12O/c1-3-7-11(8-4-1)13-14(15-13)12-9-5-2-6-10-12/h1-10,13-14H/t13-,14+

SMILES string

O1[C@H]([C@H]1c2ccccc2)c3ccccc3

InChI key

ARCJQKUWGAZPFX-OKILXGFUSA-N

assay

97%

mp

38-40 °C (lit.)

storage temp.

2-8°C

Quality Level

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

228.2 °F - closed cup

flash_point_c

109 °C - closed cup

ppe

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

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Paloma Vidal et al.
The Journal of organic chemistry, 72(9), 3166-3170 (2007-03-10)
This study presents a simple method for measuring long-range heteronuclear coupling constants between protons and proton-bearing carbons. The approach involves recording two conventional 1D-TOCSY experiments in which the offset of the selective proton pulse is set on the low- and
Ylva Ivarsson et al.
Biochimica et biophysica acta, 1770(9), 1374-1381 (2007-08-11)
Based on the crystal structure of human glutathione transferase M1-1, cysteine residues were introduced in the substrate-binding site of a Cys-free mutant of the enzyme, which were subsequently alkylated with 1-iodoalkanes. By different combinations of site-specific mutations and chemical modifications
S Bernardini et al.
Mutagenesis, 16(3), 277-281 (2001-04-26)
About 50% and 15% of Caucasians lack the glutathione S-transferase M1 (GSTM1) and T1 (GSTT1) genes and the corresponding enzyme activity, respectively. Both of these polymorphisms have been shown to affect the genotoxicity of some epoxides in cultured human lymphocytes.
Richard Lonsdale et al.
Biochemistry, 51(8), 1774-1786 (2012-01-28)
Soluble epoxide hydrolase (sEH) is an enzyme involved in drug metabolism that catalyzes the hydrolysis of epoxides to form their corresponding diols. sEH has a broad substrate range and shows high regio- and enantioselectivity for nucleophilic ring opening by Asp333.
Kouhei Shimomura et al.
Nature chemistry, 6(5), 429-434 (2014-04-24)
In the chromatographic separation of enantiomers the order of elution is determined by the strength of diasteromeric interactions between the components of the mixture and a chiral stationary phase. For analytical purposes, it is ideal to have the minor component

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