308617
叔丁基三氯硅烷
96%
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关于此项目
线性分子式:
(CH3)3CSiCl3
化学文摘社编号:
分子量:
191.56
UNSPSC Code:
12352103
NACRES:
NA.23
PubChem Substance ID:
EC Number:
242-059-7
Beilstein/REAXYS Number:
1736174
MDL number:
InChI key
MOOUPSHQAMJMSL-UHFFFAOYSA-N
InChI
1S/C4H9Cl3Si/c1-4(2,3)8(5,6)7/h1-3H3
SMILES string
CC(C)(C)[Si](Cl)(Cl)Cl
assay
96%
form
solid
bp
132-134 °C (lit.)
mp
97-100 °C (lit.)
General description
叔丁基三氯硅烷是由三甲基氯和四氯化硅反应制得的一种叔烷基三氯硅烷。它可用于通过在DMSO中水解缩合合成叔丁基硅螯烷。
Application
研究了叔丁基三氯硅烷（tBuSiCl3）在DMSO和水中的水解缩合反应。该过程形成了tBu2Si2O(OH)4，中间体的Ti络合物产生了活性的非均相环氧化催化剂。
signalword
Danger
hcodes
Hazard Classifications
Flam. Sol. 1 - Skin Corr. 1B
supp_hazards
存储类别
4.1B - Flammable solid hazardous materials
wgk
WGK 3
flash_point_f
104.0 °F - closed cup
flash_point_c
40 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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Pescarmona PP, et al.
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Silsesquioxane-Based Homogeneous and Heterogeneous Epoxidation Catalysts Developed by Using High-Speed Experimentation
Pescarmona PP, et al.
Chemistry?A European Journal , 10(7), 1657-1665 (2004)
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Yarosh OG, et al.
Russ. J. Gen. Chem., 75(5), 714-718 (2005)
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